Fosetyl aluminum

Fosetyl aluminum Basic information
Product Name:Fosetyl aluminum
Synonyms:32545rp;alietteextra;aluminiumphosethyl;Fosetyl Aluminiun;Aluminum tris(ethoxyphosphinate);Tris(phosphonic acid ethyl) aluminum salt;fosetyl alu.;Aluminiumtriethylphosphonate
CAS:39148-24-8
MF:C6H18AlO9P3
MW:354.1
EINECS:254-320-2
Product Categories:Pharmaceutical intermediates;Alphabetic;F;FM - FZPesticides;Fungicides;Organophosphorus;FUNGICIDE
Mol File:39148-24-8.mol
Fosetyl aluminum Structure
Fosetyl aluminum Chemical Properties
Melting point >300°
vapor pressure < 10-7 Pa (25 °C)
storage temp. 0-6°C
solubility Soluble in DMSO
pka4.7
Water Solubility 110 g l-1 (20 °C)
form solid
Stability:Hygroscopic
EPA Substance Registry SystemFosetyl-Al (39148-24-8)
Safety Information
Hazard Codes Xi
Risk Statements 41
Safety Statements 26-39
RIDADR UN2783 (solid); UN3018 (liquid
RTECS SZ9640000
Hazardous Substances Data39148-24-8(Hazardous Substances Data)
ToxicityLD50 in rats, mice, Japanese quail, rabbits (mg/kg): 5800, 3700, 4997, 2680 orally; LD50 i.p. in rats: 550 mg/kg (Williams)
MSDS Information
ProviderLanguage
Chipco aliette WDG English
Fosetyl aluminum Usage And Synthesis
Chemical PropertiesWhite, crystalline solid or powder. Odorless.
UsesFosetyl-aluminium (fosetyl-Al) is a systemic fungicide effective in controlling various Phycomycete diseases, in particular the downy mildews, Phyfophfhora and Pythium spp. It has also shown useful activity against several bacterial plant pathogens (e.g. Erwinia amylovara). It is widely used on a variety of crops including vines, fruit (bananas, citrus, pineapples, avocados, stone fruit and pome fruit), berries, vegetables, hops, ornamentals and turf.
UsesAgricultural fungicide.
UsesFosetyl Aluminum is a fungicide. It is highly inhibitory in vitro against several species of Phytophthora.
Agricultural UsesFosetyl aluminum can be used as Fungicide: used on fruits, vegetables and nut crops; also on ornamentals and greenhouse products.
Trade name32545 R®; ALIETTE®; ALIETTE® 80 WG; CHIPCO® ALIETTE WDG; EFOSITE-AL®; EFOSITE ALUMINUM®; EPAL®; LS-74783®; MIKAL®
Potential ExposureOrganophosphate fungicide used on fruits, vegetables and nut crops; also on ornamentals and greenhouse products.
Environmental FatePlant. Felsot and Pedersen (1991) reported that fosetyl-aluminum degrades in plants forming phosphonic acid which ionizes to the dianion phosphonate, HPO3–2.
Metabolic pathwayFosetyl-Al undergoes rapid and extensive degradation and metabolism in soil, plants and animals. Cleavage of the P-O-ethyl linkage yielded phosphorous acid, ethanol and naturally incorporated components as the terminal products (Scheme 1).
ShippingUN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
DegradationAqueous solutions of fosetyl-Al undergo rapid degradation in strong acidic and alkaline conditions (1) with observed DT50 values of 5 days (pH 3) to 13 days (pH 13) but exhibit higher stability at pH values closer to neutrality (Bertrand et al., 1981). However, the results of biodegradability studies suggest that fosetyl-Al is readily biodegradable in environmental water (Mead, 1996).
IncompatibilitiesIn the presence of strong reducing agents such as hydrides, organophosphates form highly toxic and flammable phosphine gas. Contact with oxidizers can cause the release of toxic oxides of phosphorus. Decomposes in temperatures above 260℃.
Waste DisposalDestruction by alkali hydroly sis or incineration. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by con tacting your regional EPA office.
Fosetyl aluminum Preparation Products And Raw materials
Raw materialsEthanol-->Ammonium hydroxide-->Ammonia-->Phosphorus trichloride-->Aluminum sulfate-->Diethyl phosphite-->COBALT(III) OXIDE BLACK
Preparation ProductsETHYLPHOSPHONIC ACID-->O-CRESOL-D8
Molosultap Phoxim Chlorothalonil Zoledronic acid Thiophanate-methyl Carbendazim+Fosetyl-aluminium,W.P. Triethylphosphine Ethyl phosphite Fosetyl aluminum

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