D-(+)-FUCOSE

D-(+)-FUCOSE Basic information
Product Name:D-(+)-FUCOSE
Synonyms:D-(+)-FUCOSE:6-DEOXY-D-GALACTOSE;D(+)FUCOSE extrapure;6-Deoxy-D-galactose, Rhodeose;D-Fucose ,98%;6-Deoxy-D-galactose D-(+)-Rhodeose;(α-D-Glucosido)-α-D-glucoside;(2R,3S,4S,5R)-2,3,4,5-Tetrahydroxyhexanal;aldehydo-D-fucose
CAS:3615-37-0
MF:C6H12O5
MW:164.16
EINECS:222-792-9
Product Categories:carbohydrate;Biochemistry;Deoxysugars;Fucose;Sugars;Dextrins、Sugar & Carbohydrates;Glycon Biochem
Mol File:3615-37-0.mol
D-(+)-FUCOSE Structure
D-(+)-FUCOSE Chemical Properties
Melting point 144-145 °C(lit.)
alpha D19 +127.0° (7 min) +89.4° (31 min) +77.2° (71 min) +76.0° (final value 146 min, c = 10)
Boiling point 211.61°C (rough estimate)
density 1.1738 (rough estimate)
refractive index 75.5 ° (C=10, H2O)
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 0.1 g/mL, clear, colorless
pka12.50±0.20(Predicted)
form Crystalline Powder
color White
Sensitive Hygroscopic
Merck 14,4278
BRN 1723320
LogP-2.040 (est)
CAS DataBase Reference3615-37-0(CAS DataBase Reference)
EPA Substance Registry SystemD-Galactose, 6-deoxy- (3615-37-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-36/37/39-27-26
WGK Germany 3
3-10
TSCA Yes
HS Code 29400000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
D-(+)-FUCOSE Usage And Synthesis
Chemical PropertiesWhite crystalline powder
UsesD-Fucose is a hexose deoxy sugar found on N-linked glycans that appears on the cell surface of mammalian and plant cells. D-Fucose is also the building block of fucoidan polysaccharide, an sulfated po lysaccharide found in various species of brown algae.
UsesD-Fucose is a hexose deoxy sugar found on N-linked glycans that appears on the cell surface of mammalian and plant cells. D-Fucose is also the building block of fucoidan polysaccharide, an sulfated polysaccharide found in various species of brown algae.
DefinitionChEBI: The six-membered ring form of D-fucose.
Purification MethodsCrystallise D(+)-fucose from EtOH or 95% EtOH. Its 1,2:3,4-diisopropylidene derivative has b 83-84o/0.45mm and crystallises on seeding with m 37o and[]19 -52o (melt). [Schmidt Methods in Carbohydrate Chemistry I 191 1962, Academic Press, Haskett et al. J Am Chem Soc 61 1658 1939, Beilstein 31 H 76, 1 IV 4265.]
D-(+)-FUCOSE Preparation Products And Raw materials
Raw materialsNEORUSCOGENIN-->alpha-L-Rhamnose
Preparation Products6-Deoxy-D-tagatose
D-(+)-GALACTOSE ALPHA-1-D-GALACTOPYRANOSYL-4-O-[1-(2-OCTADECYLTHIOETHYL)-(BETA-D-GALACTOPYRANOSIDE)] D(+)-Raffinose pentahydrate CALCIUM GALACTONATE MUCIC ACID 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-GALACTOPYRANOSE 1-O-ETHYL-[A-1-D-GALACTOPYRANOSYL-(4-(BETA-1-D-GALACTOPYRANOSIDE))] 6-DEOXY-6-FLUORO-D-GALACTOSE CALCIUM-D-GALACTONATE PENTAHYDRATE 4-O-(A-D-GALACTOPYRANOSYL)-D-GALACTOSE D-(+)-FUCOSE ALPHA-D-GALACTOPYRANOSYLPHENYL ISOTHIOCYANATE 4-METHYLUMBELLIFERYL-ALPHA-D-GALACTOPYRANOSIDE METHYL-ALPHA-D-GALACTOPYRANOSIDE STACHYOSE 1,2,3,4-TETRA-O-ACETYL-6-DEOXY-6-FLUORO-ALPHA-D-GALACTOPYRANOSE 6-Deoxy-1,2:3,4-di-O-isopropylidene-6-iodo-ALPHA-D-galactopyranose O-2,3,4,6-tetra-O-acetyl-alpha-D-galactopyranosyl-(1->6)-1,3,4-tri-O-acetyl-beta-D-fructofuranosyl-alpha-D-glucopyranoside tetraacetate

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