ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic alcohol 4-Bromo-4'-hydroxybiphenyl

4-Bromo-4'-hydroxybiphenyl

4-Bromo-4'-hydroxybiphenyl Basic information
Product Name:4-Bromo-4'-hydroxybiphenyl
Synonyms:4'-BROMOBIPHENYL-4-OL;4-BROMO-4'-HYDROXYBIPHENYL;4-HYDROXY-4'-BROMOBIPHENYL;4-(4-BROMPHENYL)-PHENOL;4-(4-BROMOPHENYL)PHENOL;4- hydroxyl-4’-bromobiphenyl;4'-Bromo-(1,1'-biphenyl)-4-ol;4-(4-Bromophenyl)phenol,97%
CAS:29558-77-8
MF:C12H9BrO
MW:249.1
EINECS:608-376-3
Product Categories:Bromine Compounds;Phenols;Bifunctional Compounds (Building Blocks for Liquid Crystals);Biphenyls (Building Blocks for Liquid Crystals);Building Blocks for Liquid Crystals;Functional Materials;Phenols (Building Blocks for Liquid Crystals);B;Stains and Dyes;Stains&Dyes, A to
Mol File:29558-77-8.mol
4-Bromo-4'-hydroxybiphenyl Structure
4-Bromo-4'-hydroxybiphenyl Chemical Properties
Melting point 164-166 °C(lit.)
Boiling point 355.5±17.0 °C(Predicted)
density 1.4188 (rough estimate)
refractive index 1.5130 (estimate)
storage temp. Sealed in dry,Room Temperature
pka9.70±0.15(Predicted)
form powder to crystal
color White to Almost white
Water Solubility Soluble in water (partly), and methanol.
CAS DataBase Reference29558-77-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29081990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-Bromo-4'-hydroxybiphenyl Usage And Synthesis
Chemical PropertiesWhite or cream powder
UsesA biphenyl starting material. 4?-Bromo-(1,1?-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4?-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4?-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4'-hydroxybiphenyl This was prepared from 4-bromo-4'-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4?-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF).
4-BROMO-4'-METHOXY-2'-METHYLBIPHENYL 4-BROMO-3'-FLUORO-4'-METHOXYBIPHENYL 4-ACETOXY-4'-BROMOBIPHENYL 4'-BROMO-4-(TRIFLUOROMETHOXY)BIPHENYL Bifendate 3-BENZYLOXY-4'-BROMO-4-METHOXY-BIPHENYL 3-BROMO-4-HYDROXYBIPHENYL [(4'-bromo-1,1'-biphenyl-4-yl)oxy]acetic acid 4-Benzyloxy-4'-bromo-biphenyl trans-Bifenthtin 4-(BENZYLOXY)-4'-BROMO-2',3',5',6'-TETRAFLUORO-1,1'-BIPHENYL 2,3,3',4,4',5-HEXACHLOROBIPHENYL 2-Bromobiphenyl 4-Bromo-4'-methoxybiphenyl 4-BROMO-3',4'-(METHYLENEDIOXY)BIPHENYL 4-Bromo-4'-hydroxybiphenyl FIREMASTER BP-6 Decabromodiphenyl oxide
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