m-Nitrobenzoyl chloride

m-Nitrobenzoyl chloride Basic information
Product Name:m-Nitrobenzoyl chloride
Synonyms:3-NITROBENZOYL CHLORIDE;LABOTEST-BB LTBB000612;M-NITROBENZOYL CHLORIDE;m-Nitrobenzoylchroride;META NITRO BENZOYL CHLORIDE;3-NITROBENZOYL CHLORIDE 99+%;3-Nitrobenzoyl chloride,98%;m-Nitrobenzoyl chlor
CAS:121-90-4
MF:C7H4ClNO3
MW:185.56
EINECS:204-505-9
Product Categories:Acid Halides;Building Blocks;Acid Halides;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Carbonyl Compounds;Organic Building Blocks
Mol File:121-90-4.mol
m-Nitrobenzoyl chloride Structure
m-Nitrobenzoyl chloride Chemical Properties
Melting point 31-34 °C(lit.)
Boiling point 275-278 °C(lit.)
density 1.42
refractive index 1.5810 (estimate)
Fp >230 °F
solubility soluble in Ether,Benzene,Toluene
form Low Melting Solid
color Brown
Specific Gravity1.59
Water Solubility decomposes
Sensitive Moisture Sensitive
BRN 777186
CAS DataBase Reference121-90-4(CAS DataBase Reference)
NIST Chemistry ReferenceBenzoyl chloride, 3-nitro-(121-90-4)
EPA Substance Registry Systemm-Nitrobenzoyl chloride (121-90-4)
Safety Information
Hazard Codes C
Risk Statements 5-21-34-37
Safety Statements 26-36/37/39-45-7/9-38
RIDADR UN 2923 8/PG 3
WGK Germany 3
RTECS DM6646000
9-19-21
Hazard Note Corrosive
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29163900
MSDS Information
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m-Nitrobenzoyl chloride Usage And Synthesis
Chemical PropertiesBROWN LOW MELTING SOLID
UsesManufacture of dyes for fabrics and color photography, intermediate in preparation of pharmaceuticals.
Uses3-Nitrobenzoyl Chloride is an useful building block reagent in the preparation of organic compounds of research interest.
Uses3-Nitrobenzoyl chloride was used in the synthesis of 3-aminobenzamide. It was also used to synthesize potential carbocyclic minor groove binders.
General DescriptionYellow to brown liquid. Unstable at room temperatures; requires refrigeration when not in use.
Air & Water ReactionsMay be unstable to prolonged exposure to air. Decomposes in water and alcohol. .
Reactivity Profilem-Nitrobenzoyl chloride is incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react with reducing agents. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
HazardToxic by ingestion.
Health HazardACUTE/CHRONIC HAZARDS: m-Nitrobenzoyl chloride is unstable at room temperature or when exposed to sources of ignition. When heated to decomposition it emits highly toxic fumes. It will react with water or steam to produce toxic and corrosive fumes.
Fire Hazardm-Nitrobenzoyl chloride is combustible.
m-Nitrobenzoyl chloride Preparation Products And Raw materials
Raw materialsThionyl chloride-->Benzene-->3-Nitrobenzoic acid-->2-Nitrobenzoyl chloride-->Benzoyl chloride
Preparation Products3-Nitrobenzaldehyde-->3-NITROBENZHYDRAZIDE-->3-Nitrobenzyl alcohol-->3-AMINO-N,N-DIMETHYLBENZYLAMINE
Methylene Chloride 4-(Chloromethyl)benzoyl chloride 2,3,4,5-Tetrafluorobenzoyl chloride P-NITROBENZOYL CHLORIDE,Nitrobenzoyl chloride, 4-,4-NITROBENZOYL CHLORIDE Calcium chloride Sodium chloride 3-METHOXYBENZOYL CHLORIDE 3-Nitrobenzenesulfonyl chloride o-Toluoyl chloride Choline chloride 3,5-Dinitrobenzoyl chloride Ammonium chloride 4-Chlorobenzoyl chloride Benzoyl chloride Potassium chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile p-Toluoyl chloride alpha,alpha,alpha-Trifluoro-o-toluoyl chloride

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