2-Bromopentane

2-Bromopentane Basic information
Product Name:2-Bromopentane
Synonyms:(+/-)-2-PENTYL BROMIDE;2-PENTYL BROMIDE;(+/-)-2-BROMOPENTANE;2-BROMOPENTANE;sec-Pentylbromide;2-Bromopentane, tech., 90%;2-BROMOPENTANE MIN 955;2-Bromopentane (contains ca. 12% 3-Bromopentane)
CAS:107-81-3
MF:C5H11Br
MW:151.04
EINECS:203-521-3
Product Categories:Aliphatics;Intermediates;Miscellaneous Reagents
Mol File:107-81-3.mol
2-Bromopentane Structure
2-Bromopentane Chemical Properties
Melting point -95.5 °C
Boiling point 116-117 °C(lit.)
density 1.223 g/mL at 25 °C(lit.)
refractive index n20/D 1.441(lit.)
Fp 69 °F
storage temp. Flammables area
solubility Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form Liquid
color Clear
Water Solubility practically insoluble
BRN 1718829
Stability:Stable. Highly flammable. Incompatible with strong bases, strong oxidizing agents.
InChIKeyLGAJYTCRJPCZRJ-UHFFFAOYSA-N
CAS DataBase Reference107-81-3(CAS DataBase Reference)
NIST Chemistry ReferencePentane, 2-bromo-(107-81-3)
EPA Substance Registry SystemPentane, 2-bromo- (107-81-3)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38
Safety Statements 16-26-36/37/39
RIDADR UN 2343 3/PG 2
WGK Germany 3
RTECS RZ9800000
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29033990
MSDS Information
ProviderLanguage
2-Bromopentane English
SigmaAldrich English
ACROS English
ALFA English
2-Bromopentane Usage And Synthesis
Chemical Properties2-bromopentane is a colorless to yellow-colored liquid with a strong odor. It is an optically active compound because it contains an asymmetric carbon (chiral carbon). An asymmetric carbon is carbon atom that is attached to four different types of atoms or groups of atoms. In 2-Bromopentance, the central carbon atom is attached to four different types of atoms (CH2, CH3, Br, H), hence it is an optically active compound.
UsesUsed as a chemical intermediate.
General DescriptionA colorless to yellow-colored liquid with a strong odor. Flash point 90°F. Slightly denser than water and insoluble in water. Vapors heavier than air. May irritate skin and eyes. In high concentrations the vapors may be narcotic.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity Profile2-Bromopentane is incompatible with strong oxidizing and reducing agents. Also incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Health HazardIrritating to eyes, nose, throat, and upper respiratory tract. Causes skin irritation.
Safety ProfilePoison by intraperitoneal route. Mildly toxic by inhalation. A local irritant and narcotic in high concentration. Ingestion can cause liver damage. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC.
Purification MethodsDry it over K2CO3 and distil it through a short Vigreux column (p 11). [IR: Pines et al. J Am Chem Soc 74 4063 1952, Brown & Wheeler J Am Chem Soc 78 2199 1956, Beilstein 1 IV 312.]
iso-Bromopentane 3-Bromopentane, containing about 10% 2-Bromopentane, 90%,3-Bromopentane (contains ca. 14% 2-Bromohexane),3-BROMOPENTANE 1,4-Dibromopentane 2,2-DIMETHYLPROPANE [S,(+)]-2-Bromopentane Sodium pentanesulfonate (R)-4,5-ISOPROPYLIDENE-1-BROMOPENTANE Methylcyclopentane 2,4-DIBROMOPENTANE 2-Methylbutane Pentane 1-BROMOPENTANE,Bromopentane, 1-,1-BROMOPENTANE pure 2-Bromopentane BROMOPENTANE Cyclopentane 1-BROMOPENTANE-D1 Bromocyclopentane 1-BROMOPENTANE-D11

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