Tetramethoxymethane

Tetramethoxymethane Basic information
Product Name:Tetramethoxymethane
Synonyms:Tetramethyl orthocarbonate 98%;Dimethoxymethylal;NSC 359558;Orthocarbonic acid, tetramethyl ester;Methane, tetramethoxy-;TETRAMETHOXYMETHANE;TETRAMETHYL ORTHOCARBONATE
CAS:1850-14-2
MF:C5H12O4
MW:136.15
EINECS:217-438-5
Product Categories:Acetals/Ketals/Ortho Esters;Building Blocks;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;Acetals/Ketals/Ortho Esters;Organic Building Blocks;Oxygen Compounds
Mol File:1850-14-2.mol
Tetramethoxymethane Structure
Tetramethoxymethane Chemical Properties
Melting point -5 °C (lit.)
Boiling point 114 °C (lit.)
density 1.023 g/mL at 25 °C (lit.)
refractive index n20/D 1.385(lit.)
Fp 44 °F
storage temp. Refrigerator
solubility Chloroform, Ethyl Acetate, Methanol
form Liquid
color Colorless
Sensitive Moisture Sensitive
BRN 1737682
CAS DataBase Reference1850-14-2(CAS DataBase Reference)
NIST Chemistry ReferenceTetramethoxymethane(1850-14-2)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-37
RIDADR UN 3272 3/PG 2
WGK Germany 3
21
HS Code 2909.19.6000
HazardClass 3.1
PackingGroup II
MSDS Information
ProviderLanguage
Tetramethyl orthocarbonate English
SigmaAldrich English
Tetramethoxymethane Usage And Synthesis
UsesTetramethoxymethane has application within an electrolyte solution for the use of rechargeable lithium batteries. It has also been used as a reactant in the synthesis of novel anti-HIV-1 compounds.
Purification MethodsTetramethyl orthocarbonate (methyl orthocarbonate, tetramethoxy methane) [1850-14-2] M 136.2, m -5.6o, -5o, -2o, b 113.5o/760mm, 113.5 -114o/755mm, 112-114o/atm, d 4 1.0202, n D 1.3860. Purify it in the same way as for tetraethyl orthocarbonate. [Smith Acta Chem Scand 10 1006 1956, Tiekelmann & Post J Org Chem 13 266 1948, Kantlehner et al. Synthesis 73 1977, Beilstein 3 IV 4.]
1,1,1-Trimethoxypentane Tetraethyl orthocarbonate Trimethoxymethane Trimethyl orthoacetate Triethyl orthobenzoate Triethyl orthoacetate TETRA-N-PROPOXYMETHANE 2,2',2'',2'''-[methanetetrayltetrakis(oxy)]tetrakispropane Calcium carbonate Emetine dihydrochloride Lithium carbonate Polycarbonate Tetramethoxymethane TETRAKIS(2,2,3,3-TETRAFLUOROPROPYL)ORTHOCARBONATE Sodium bicarbonate TETRAKIS(2,2,3,3,4,4,5,5,6,6,7,7-DODECAFLUOROHEPTYL)ORTHOCARBONATE TETRAKIS(2,2,3,3,4,4,5,5-OCTAFLUOROPENTYL)ORTHOCARBONATE TETRAMETHYL-O-CARBONATE = TETRAMETHOXYMETHANE ()

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