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| | METHYLENECYCLOHEXANE Basic information |
| | METHYLENECYCLOHEXANE Chemical Properties |
| Melting point | -106.7°C | | Boiling point | 102-103 °C (lit.) | | density | 0.8 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.449(lit.) | | Fp | 20 °F | | storage temp. | 2-8°C | | form | Liquid | | color | Clear colorless | | BRN | 773760 | | Stability: | Stable. Highly flammable. Incompatible with strong oxidizing agents. Refrigerate. | | EPA Substance Registry System | Cyclohexane, methylene- (1192-37-6) |
| Hazard Codes | F,Xn | | Risk Statements | 11-65 | | Safety Statements | 16-23-24/25-62 | | RIDADR | UN 3295 3/PG 2 | | WGK Germany | 3 | | HazardClass | 3.1 | | PackingGroup | II | | HS Code | 29021900 |
| | METHYLENECYCLOHEXANE Usage And Synthesis |
| Chemical Properties | colourless liquid | | Uses | Methylenecyclohexane is excellent building block for organic molecules. | | Synthesis Reference(s) | Journal of the American Chemical Society, 100, p. 3611, 1978 DOI: 10.1021/ja00479a061
The Journal of Organic Chemistry, 48, p. 326, 1983 DOI: 10.1021/jo00151a010
Tetrahedron Letters, 25, p. 4901, 1984 DOI: 10.1016/S0040-4039(01)91254-7 | | General Description | Methylenecyclohexane ring is obtained by 1,4-addition of 4-pentenylmagnesium bromide to 2-cyano-2-cycloalkenones followed by a Pd(II)-mediated oxidative cyclization. It undergoes gas phase ozonolysis to form secondary organic aerosol (SOA). |
| | METHYLENECYCLOHEXANE Preparation Products And Raw materials |
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