ChemicalBook Product Catalog Organic Chemistry Phosphines BORANE-DIPHENYLPHOSPHINE COMPLEX

BORANE-DIPHENYLPHOSPHINE COMPLEX

BORANE-DIPHENYLPHOSPHINE COMPLEX Basic information
Product Name:BORANE-DIPHENYLPHOSPHINE COMPLEX
Synonyms:PHENYLPHOSPHINE BORANE COMPLEX;BORANE-DIPHENYLPHOSPHINE COMPLEX;DIPHENYLPHOSPHINE-BORANE COMPLEX;Borane diphenylphosphine;(Diphenylphosphine)borane;(Diphenylphosphine)trihydroboron;(T-4)-(Diphenylphosphine)trihydroboron;Borane-diphenylphosphine complex,94%
CAS:41593-58-2
MF:C12H14BP
MW:200.02
EINECS:
Product Categories:BoranesCatalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;Reduction;Synthetic Reagents
Mol File:41593-58-2.mol
BORANE-DIPHENYLPHOSPHINE COMPLEX Structure
BORANE-DIPHENYLPHOSPHINE COMPLEX Chemical Properties
Melting point 47-50 °C(lit.)
Boiling point 148-150 °C10 mm Hg(lit.)
storage temp. water-free area
form Solid
color White to off-white
Sensitive Moisture Sensitive
Safety Information
Hazard Codes F
Risk Statements 15
Safety Statements 43
RIDADR UN 2813 4.3/PG 2
WGK Germany 3
HazardClass 4.3
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
BORANE-DIPHENYLPHOSPHINE COMPLEX Usage And Synthesis
Chemical Propertieswhite to off-white powder or crystals
UsesReactant for:
  • Nucleophilic addition reactions (anion)
  • Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
  • Deprotonation reactions
  • Catalytic coupling with alkynyl bromides
  • Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
  • Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
  • Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases
BORANE-DIPHENYLPHOSPHINE COMPLEX Preparation Products And Raw materials
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE TRIPHENYLBORANE-TRIPHENYLPHOSPHINE COMPLEX BENZYLTRIPHENYLPHOSPHONIUM BOROHYDRIDE BIS(TRIPHENYLPHOSPHINE)IMINIUM BOROHYDRIDE (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE AURORA KA-510 [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE 4-CHLOROBENZYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE, 98 Phosphonium, 1,3-dithiolan-2-yltriphenyl-, tetrafluoroborate(1-) BORANE-DIPHENYLPHOSPHINE COMPLEX 1,3-Benzodithiol-2-yltriphenyl phosphonium tetrafluoroborate BORANE-TRIPHENYLPHOSPHINE COMPLEX BENZYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE 1-CARBETHOXYCYCLOPROPYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NORBORNADIENE RHODIUM TETRAFLUOROBORATE Bis-(triphenylphosphino)-cuprous borohydride Tetraphenylphosphonium tetrafluoroborate TETRAPHENYLPHOSPHONIUM TETRAPHENYLBORATE
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