trans-1,4-Diaminocyclohexane

trans-1,4-Diaminocyclohexane Basic information

Product Name:	trans-1,4-Diaminocyclohexane
Synonyms:	TIMTEC-BB SBB008553;TRANS-1,4-CYCLOHEXYLDIAMINE;TRANS-1,4-DIAMINOCYCLOHEXANE;TRANS-HEXAHYDRO-1,4-PHENYLENEDIAMINE;TRAN(S)-CYCLOHEXANE-1,4-DIAMINE;trans-1,4-Diaminocyclohexane,99%;trans-1,4-Diaminocyclohexane ,98%;Trans 1,4-Diaminocyc
CAS:	2615-25-0
MF:	C6H14N2
MW:	114.19
EINECS:	640-403-4
Product Categories:	Heterocycles series
Mol File:	2615-25-0.mol

trans-1,4-Diaminocyclohexane Chemical Properties

Melting point	67-72 °C
Boiling point	197 °C(lit.)
density	0.939±0.06 g/cm3(Predicted)
vapor pressure	18 mm Hg ( 87.2 °C)
Fp	71 °C
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	soluble in Methanol
pka	10.78±0.70(Predicted)
form	Crystals or Chunks
color	Off-white to brown
explosive limit	6%
BRN	2801657
InChI	InChI=1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6-
InChIKey	VKIRRGRTJUUZHS-IZLXSQMJSA-N
SMILES	[C@@H]1(N)CC[C@@H](N)CC1
CAS DataBase Reference	2615-25-0(CAS DataBase Reference)
EPA Substance Registry System	1,4-Cyclohexanediamine, trans- (2615-25-0)

Safety Information

Hazard Codes	C
Risk Statements	22-34-20/21/22
Safety Statements	26-36/37/39-45
RIDADR	UN 3259 8/PG 2
WGK Germany	2
F	10-34
Autoignition Temperature	680 °F
HazardClass	8
PackingGroup	II
HS Code	29213000

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

trans-1,4-Diaminocyclohexane Usage And Synthesis

Chemical Properties	off-white to brown crystals or chunks
Uses	trans-1,4-Diaminocyclohexane was used in preparation of fully aliphatic polyimides. It was employed as the structure-directing agent in the synthesis of novel two-dimensional layered zinc phosphate.
Uses	trans-1,4-diaminocyclohexane be used as organic intermediates and epoxy curing agents.
Purification Methods	Recrystallise the diamine from pet ether under N2 or Ar as it should be an even stronger base than the above 1,2-diamine isomers. It distils under N2. Store in the dark under N2. [Beistein 13 I 3, 13 III 11.]

trans-1,4-Diaminocyclohexane Preparation Products And Raw materials

Raw materials	Palladium-->Sodium borohydride-->Benzylamine-->Methylcyclohexane-->1,4-Cyclohexanedione-->3-Methylbenzoyl chloride-->CIS-1,4-CYCLOHEXANEDIAMINE-->trans-4-Aminocyclohexanol-->4-Nitrophenol
Preparation Products	N-(trans-4-aMinocyclohexyl)-AcetaMide

3-Fluoro-3-demethoxysporaricin A 2,10-DIPHENYL-1,2,4,9,10,12-HEXAAZADISPIRO[4.2.4.2]TETRADECANE-3,11-DIONE TRANS-N-BOC-1,4-CYCLOHEXANEDIAMINE BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE 2-Amino-5-[[[(aminocarbonyl)amino]acetyl]methylamino]-1-O-(2,6-diamino-2,3,4,6,7-pentadeoxy-β-L-lyxo-heptopyranosyl)-4-O-methyl-2,3,5-trideoxy-D-allo-inositol BOC-TRANS-1,4-AMINO-1-CYCLOHEXANE CARBOXYLIC ACID Water ring vacuum pump 2-(4-CHLOROPHENYL)-10-PHENYL-1,2,4,9,10,12-HEXAAZADISPIRO[4.2.4.2]TETRADECANE-3,11-DIONE 1-Epi-2-deoxyfortimicin A 2-(1,1-DIOXOTETRAHYDRO-1H-1LAMBDA6-THIOPHEN-3-YL)-10-PHENYL-1,2,4,9,10,12-HEXAAZADISPIRO[4.2.4.2]TETRADECANE-3,11-DIONE Cyclohexane, 1,4-diisocyano- (9CI) NYLON 6/6 2,3,5,6-TETRAHYDROXY-1,4-DINITROCYCLOHEXANE DIHYDRATE trans-1,4-Diaminocyclohexane, N1-BOC protected trans,trans-2,4-Undecadienal TRANS-N-FMOC-1,4-CYCLOHEXANEDIAIME HYDROCHLORIDE 1,4-CYCLOHEXANEDIAMINE 4-(N-T-BUTOXYCARBONYLAMINO)CYCLOHEXYLISOCYANIDE

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