ChemicalBook Product Catalog Chemical Reagents Organic reagents Cyanide / nitrile 5-CYANO-1-PENTYNE

5-CYANO-1-PENTYNE

5-CYANO-1-PENTYNE Basic information
Product Name:5-CYANO-1-PENTYNE
Synonyms:5-HEXYNENITRILE;5-HEXYNNITRILE;5-CYANO-1-PENTYNE;5-HEXYNENITRILE 98%;5-Hexyne-1-nitrile;5-Hexynenitrile,98%;5-Hexynenitrile, 98% 1GR;hex-5-ynenitrile
CAS:14918-21-9
MF:C6H7N
MW:93.13
EINECS:
Product Categories:
Mol File:14918-21-9.mol
5-CYANO-1-PENTYNE Structure
5-CYANO-1-PENTYNE Chemical Properties
Boiling point 115-117 °C(lit.)
density 0.889 g/mL at 25 °C(lit.)
refractive index n20/D 1.44(lit.)
Fp 108 °F
storage temp. 2-8°C
form Liquid
color Clear colorless to amber
Water Solubility Miscible with water.
BRN 1735926
CAS DataBase Reference14918-21-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 10-20/21/22-36/37/38
Safety Statements 16-23-26-28-36/37/39
RIDADR UN 1993 3/PG 3
WGK Germany 3
F 10-19-23
HazardClass 3
PackingGroup III
HS Code 29269095
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
5-CYANO-1-PENTYNE Usage And Synthesis
Chemical Propertiesclear colourless to amber liquid
Uses5-Hexynenitrile is used in the preparation of annelated symmetric and asymmetric 3,3'-disubstituted 2,2'-bipyridines by cobalt(I)-catalyzed [2+2+2] cycloadditions with 1,3-diynes. Further, it reacts with 3-bromo-pyridine to prepare 6-(3-pyridinyl)-5-hexynenitrile.
5-CYANO-1-PENTYNE Preparation Products And Raw materials
Preparation Products5-KETOHEXANENITRILE-->5-Chlorohex-5-enenitrile
7-CYANO-3-HEPTYNE CYCLOHEXYLIDENECYANOACETIC ACID RARECHEM AQ BC 8112 RARECHEM AQ BC 8094 2-AMINOPENT-4-YNENITRILE 5-CYANO-1-PENTYNE RARECHEM AQ BC 8113 CYCLOHEXYL CYANOACETATE 6-(2-DIMETHYLAMINO-PHENYL)-HEX-5-YNENITRILE 1-PENTYNE
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