ChemicalBook Product Catalog Chemical Reagents Organic reagents Polycyclic compound 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE

5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE

5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Basic information
Product Name:5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE
Synonyms:2,7,12,17-tetrakis(pyridin-4-yl)-21,22,23,24-tetraazapentacyclo[16.2.1.1^{3,6}.1^{8,11}.1^{13,16}]tetracosa-1,3,5,7,9,11,13,15,17,19-decaene;5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine 97%;COTPYP;5,10,15,20-tetrapyridin-4-yl-21,22-dihydroporphyrin;5,10,15,20-Tetra(4-pyridyl);23h-porphine,5,10,15,20-tetra-4-pyridinyl-21;MESO-TETRA(4-PYRIDYL)PORPHINE;5,10,15,20-TETRAKIS-(4-PYRIDYL)-21,23H-PORPHYRIN
CAS:16834-13-2
MF:C40H26N8
MW:618.69
EINECS:240-858-5
Product Categories:organic building block;Standards and Kits;Biochemistry;Synthetic Porphyrins;porphine (porphyrin) ligand;Analytical Chemistry;Chelating Reagents;Porphines;Porphyrin Building Blocks;Porphyrins;Natural Porphyrins and Derivitives;Organics
Mol File:16834-13-2.mol
5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Structure
5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Chemical Properties
density 1.335±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
form Powder
color purple
BRN 635257
InChIKeyDNZSHSJERXNJGX-XXDGMDECSA-N
EPA Substance Registry System21H,23H-Porphine, 5,10,15,20-tetra-4-pyridinyl- (16834-13-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 10
HS Code 29333990
MSDS Information
ProviderLanguage
SigmaAldrich English
5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Usage And Synthesis
Chemical PropertiesPurple to dark purple solid
Uses5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine is used in the making of coordination catalysts.
General Description5,10,15,20-tetra-4-pyridyl-21H,23H-porphine (H2TPyP)?can react with [Re6(μ3-Se)8(Pet3)5(NCMe]2+ and 2,4,6-tri-4-pyridyl-1,3,5-triazine to form tri- and tetra complexes. 1 Trace amounts of nitroaromatic explosives can be detected by porphyrin functionalized graphene. It behaves as a sensitive amperometric sensor. 2
Purification MethodsPurify it by chromatography on alumina (neutral, Grade I), with CHCl3/MeOH (80:20) followed by recrystallisation from CH2Cl2/MeOH [Yamashita et al. J Phys Chem 91 3055 1987]. [Kalyanasundaram Inorg Chem 23 2453 1984, Okuno et al. Synthesis 537 1980.]
5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Preparation Products And Raw materials
Raw materialsMethyl 4-formylbenzoate-->5-(4-Pyridyl)dipyrromethane
Preparation Products5,10,15,20-TETRAKIS-(N-METHYL-4-PYRIDYL)-21,23H-PORPHYRIN TETRACHLORIDE
ZINC PORPHYRIN DIMER meso-Tetra (4-chlorophenyl) porphine 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE 5,10,15,20-TETRAKIS(4-FLUOROPHENYL)-21H,23H-PORPHINE) 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE 5,10,15,20-tetra(3-hydroxyphenyl)porphyrin 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE 5,10,15,20-TETRA(4-DIMETHYLAMINOPHENYL)PORPHYRIN TPP meso-Tetra(4-carboxyphenyl)porphine 5,10,15,20-TETRAKIS(4-AMINOPHENYL)-21H,23H-PORPHINE 3-PYRIDIN-4-YLANILINE SALOR-INT L163317-1EA 5,10,15,20-TETRAKIS-(N-METHYL-4-PYRIDYL)-21,23H-PORPHYRIN TETRACHLORIDE PORPHINE ZINC 5,10,15,20-TETRA(4-PYRIDYL)-21 H,23 H-PORPHINE TETRAKIS(METHOCHLORIDE) MANGANESE(III) 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE CHLORIDE TETRAKIS(METHOCHLORIDE) TMPYP
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