ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon nitrification 3-Nitrophenylboronic acid

3-Nitrophenylboronic acid

3-Nitrophenylboronic acid Basic information
Product Name:3-Nitrophenylboronic acid
Synonyms:(3-nitrophenyl)-boronicaci;m-nitro-benzeneboronicaci;m-nitrobenzeneboronicacid;3-NITROPHENYLBORIC ACID;3-NITROPHENYLBORONIC ACID;3-NITROBENZENEBORONIC ACID;AKOS BRN-0128;M-NITROPHENYLBORONIC ACID
CAS:13331-27-6
MF:C6H6BNO4
MW:166.93
EINECS:
Product Categories:Boronate Ester;Potassium Trifluoroborate;Aryl Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents;B (Classes of Boron Compounds);Organometallics;Boronic acids;Boronic Acid;Aryl;Organoborons;Substituted Boronic Acids;blocks;BoronicAcids;Boronic Acid series
Mol File:13331-27-6.mol
3-Nitrophenylboronic acid Structure
3-Nitrophenylboronic acid Chemical Properties
Melting point 284-285 °C (dec.) (lit.)
Boiling point 363.3±44.0 °C(Predicted)
density 1.40±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility soluble in Ethanol,Methanol,Ether
form Powder
pka6.93±0.10(Predicted)
color Light yellow to pale brown
Water Solubility soluble in hot water
Sensitive Hygroscopic
BRN 2938638
InChIKeyZNRGSYUVFVNSAW-UHFFFAOYSA-N
CAS DataBase Reference13331-27-6(CAS DataBase Reference)
EPA Substance Registry SystemBoronic acid, (3-nitrophenyl)- (13331-27-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39-36
WGK Germany 3
RTECS CY8980000
Hazard Note Harmful
TSCA T
HazardClass IRRITANT
HS Code 29310095
MSDS Information
ProviderLanguage
3-Nitrobenzeneboronic acid English
SigmaAldrich English
ACROS English
ALFA English
3-Nitrophenylboronic acid Usage And Synthesis
Chemical PropertiesWhite to light yellow crystal powde
Usessuzuki reaction
UsesCatalyzes ene carbocyclization of acetylenic dicarbonyl compounds8
Uses3-Nitrophenylboronic Acid is a general reagent the preparation of carbon coated copper nanoparticles and nanowires for usage in Suzuki cross coupling reactions. Also it has been used in the synthesis of oxygenated cabazoles.
Synthesis Reference(s)The Journal of Organic Chemistry, 49, p. 5237, 1984 DOI: 10.1021/jo00200a045
3-Nitrophenylboronic acid Preparation Products And Raw materials
Preparation Products6-(3-NITROPHENYL)-2-PYRIDINECARBOXALDEHYDE-->2-(3-AMINOPHENYL)PYRIDINE-->3-Bromonitrobenzene-->3-Nitrobenzyl alcohol-->3-AMINOBIPHENYL-->METHYL 3'-NITRO[1,1'-BIPHENYL]-3-CARBOXYLATE-->Benzene, 1-nitro-3-(pentyloxy)--->3'-NITRO[1,1'-BIPHENYL]-4-CARBONITRILE-->3-Aminobenzeneboronic acid-->3-NITRODIPHENYLAMINE
Nitrosobenzene 4-Tolylboronic acid (4-METHYL-2-NITRO)BENZENEBORONIC ACID (2-METHYL-5-NITROPHENYL)BORONIC ACID Ethyl 2-(Chlorosulfonyl)acetate 2-FLUORO-5-NITROPHENYLBORONIC ACID PINACOL ESTER 3-(N-ISOPROPYLAMINOCARBONYL)-5-NITROPHENYLBORONIC ACID 4-CARBOXY-2-NITROPHENYLBORONIC ACID Ascoric Acid 3-METHOXYCARBONYL-5-NITROPHENYLBORONIC ACID Phenylacetone 4-METHOXY-3-NITROPHENYLBORONIC ACID (3,5-DINITRO-2-METHYLPHENYL)BORONIC ACID 3-NITROPROPIONIC ACID 4-CHLORO-3-NITROPHENYLBORONIC ACID 3,5-Dimethylphenylboronic acid 3,4-DIFLUORO-5-NITROPHENYLBORONIC ACID 4-BROMO-3-NITROPHENYLBORONIC ACID
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