BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE

BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Basic information
Product Name:BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE
Synonyms:dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)-hafniu;dichlorobis(eta5-2,4-cyclopentadien-1-yl)-hafniu;Dichlorobis(eta-cyclopentadienyl)hafnium;Dichlorodicyclopentadienylhafnium;dichlorodi-pi-cyclopentadienyl-hafniu;Dichlorodi-pi-cyclopentadienylhafnium;Hafnium dicyclopentadiene dichloride;Hafnium, dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)-
CAS:12116-66-4
MF:C10H10Cl2Hf10*
MW:379.58
EINECS:235-177-5
Product Categories:metallocene;Biochemistry;Classes of Metal Compounds;Hf (Hafnium) Compounds;Metallocenes;Reagents for Oligosaccharide Synthesis;Titanocene, etc.;Transition Metal Compounds
Mol File:12116-66-4.mol
BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Structure
BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Chemical Properties
Melting point 230-233 °C
Boiling point 339.81°C (rough estimate)
solubility Soluble in aromatic solvents, chloroform; slightly soluble in THF, ether. Insolble in hexanes.
form crystal
color off-white
Sensitive Air & Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Exposure limitsACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
CAS DataBase Reference12116-66-4(CAS DataBase Reference)
NIST Chemistry ReferenceBis(«eta»5-cyclopentadienyl)hafnium dichloride(12116-66-4)
EPA Substance Registry SystemHafnium, dichlorobis(.eta.5-2,4-cyclopentadien-1-yl)- (12116-66-4)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-37/39
RIDADR UN3261
WGK Germany 3
RTECS MG4815000
10-21
TSCA Yes
HS Code 2931.90.9051
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Usage And Synthesis
Chemical Propertieswhite to light brown crystals or crystalline
UsesStarting material to prepare many kinds of hafnocene(II or IV) derivatives; in combination with AgI salt, is an effective activator for glycosyl fluoride. Pharmaceutical intermediates and alos used in chemical research.
TITANIUM NITRIDE Titanocene dichloride Titanous chloride BIS(T-BUTYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(ETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE Hafnium(IV) chloride HAFNIUM (PENTAMETHYLCYCLOPENTADIENYL)(N-PROPYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(PENTAMETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(BUTYLCYCLOPENTADIENYL)HAFNIUM(IV) DICHLORIDE 1,1'-DIPROPYLHAFNOCENE DICHLORIDE BIS(ISOPROPYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE

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