ChemicalBook Product Catalog Organic Chemistry Phosphines ALLYLDIPHENYLPHOSPHINE OXIDE

ALLYLDIPHENYLPHOSPHINE OXIDE

ALLYLDIPHENYLPHOSPHINE OXIDE Basic information
Product Name:ALLYLDIPHENYLPHOSPHINE OXIDE
Synonyms:Phosphine oxide,diphenyl-2-propen-1-yl-;ALLYLDIPHENYLPHOSPHINE OXIDE;Alydiphenylphosphine oxide;NISTC4141484;Diphenylallylphosphine oxide;[allyl(phenyl)phosphoryl]benzene;[phenyl(prop-2-enyl)phosphoryl]benzene;Diphenyl-2-propenylphosphine oxide
CAS:4141-48-4
MF:C15H15OP
MW:242.25
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
Mol File:4141-48-4.mol
ALLYLDIPHENYLPHOSPHINE OXIDE Structure
ALLYLDIPHENYLPHOSPHINE OXIDE Chemical Properties
Melting point 110-114 °C(lit.)
Boiling point 200-202 °C(Press: 2 Torr)
density 1.0769 g/cm3
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ALLYLDIPHENYLPHOSPHINE OXIDE Usage And Synthesis
UsesReactant for:
  • Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
  • Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
  • C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
  • Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
  • Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides
ALLYLDIPHENYLPHOSPHINE OXIDE Preparation Products And Raw materials
Probenazole 1-allylhydrazine hydrochloride DIETHYL ALLYLPHOSPHONATE ALLYLTRIETHOXYSILANE ALLYLDIPHENYLPHOSPHINE Allyl methyl carbonate Dimethyl allylmalonate Allicin Allyl Benzyl Ether Allylbenzene Diethyl allylmalonate ALLYLUREA Diphenylphosphine oxide 1-(DIPHENYLPHOSPHORYL)-3-PHENYLPROP-2-EN-1-OL (e,e)-2,4-Heptadienyldiphenylphosphine Oxide ALLYLDIPHENYLPHOSPHINE OXIDE tert-Butyl-{3-[2-(diphenyl-phosphinoyl)-ethylidene]-4-methylene-cyclohexyloxy}-dimethyl-silane PHOSPHINE OXIDE, [2-[3,5-BIS [[(1,1-DIMETHYLETHYL) DIMETHYLSILY]OXY]-2-METHYLENECYCLOHEXYLIDENE]ETHYL]DIPHENYL-,[3S-(1Z,3A,5B0)]
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