trans-2-Hexen-1-ol

trans-2-Hexen-1-ol Basic information
Product Name:trans-2-Hexen-1-ol
Synonyms:TRANS-2-HEXEN-1-OL 95+% FCC;trans-2-Hexen-1-ol,97%;(E)-2-hexenol,(E)-2-hexen-1-ol;2-Hexen-1-ol, (2E)-;HEXENOL TRANS-2;TRANS-2-HEXEN-1-OL WITH GC;trans-2-Hexenyl alcohol;Trans-2-Hexenol(N/A)
CAS:928-95-0
MF:C6H12O
MW:100.16
EINECS:213-191-2
Product Categories:Alphabetical Listings;Flavors and Fragrances;Acyclic;Alkenes;Organic Building Blocks;G-H;alcohol Flavor
Mol File:928-95-0.mol
trans-2-Hexen-1-ol Structure
trans-2-Hexen-1-ol Chemical Properties
Melting point 54.63°C
Boiling point 158-160 °C(lit.)
density 0.849 g/mL at 25 °C(lit.)
vapor pressure 1hPa at 20℃
FEMA 2562 | 2-HEXEN-1-OL
refractive index n20/D 1.438(lit.)
Fp 130 °F
storage temp. 2-8°C
form Liquid
pka14.45±0.10(Predicted)
color Clear colorless
Odorat 10.00 % in dipropylene glycol. fresh green leafy fruity unripe banana
Odor Typefruity
Water Solubility Slightly soluble in water
BRN 1719709
Stability:Stable. Flammable. Incompatible with strong oxidizing agents, strong acids.
LogP1.61 at 25℃
CAS DataBase Reference928-95-0(CAS DataBase Reference)
NIST Chemistry Reference2-Hexen-1-ol, (E)-(928-95-0)
EPA Substance Registry System(E)-2-Hexen-1-ol (928-95-0)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-36
RIDADR UN 1987 3/PG 3
WGK Germany 2
RTECS MP8390000
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29052900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
trans-2-Hexen-1-ol Usage And Synthesis
Chemical Propertiescolourless liquid
Chemical Properties(E)-2-Hexen-1-ol occurs in many fruits and has a fruity, green odor, which is sweeter than that of the isomeric (Z)-3- hexen-1-ol and is, therefore, preferred in aroma compositions.
Usestrans-2-Hexen-1-ol was used to evaluate the quality of protected designation of virgin olive oils by headspace solid-phase microextraction-gas chromatography using flame ionization detection and multivariate analysis. It was also used in encapsulation of vanadium catalysts in inorganic and hybrid matrices using sol-gel method.
DefinitionChEBI: 2-hexen-1-ol is a primary allylic alcohol that is 2-hexene in which a hydrogen at position 1 has been replaced by a hydroxy group. It has a role as a plant metabolite. It is an alkenyl alcohol and a primary allylic alcohol.
Synthesis Reference(s)Journal of the American Chemical Society, 93, p. 2792, 1971 DOI: 10.1021/ja00740a040
Tetrahedron Letters, 24, p. 3413, 1983 DOI: 10.1016/S0040-4039(00)86286-3
General Descriptiontrans-2-Hexen-1-ol undergoes allylic epoxidation to yield (2R,3R)-(+)-3-propyloxiranemethanol in high pressure carbon dioxide.
Biochem/physiol ActionsTaste at 2.0-9.0 ppm
TRANS-3-HEXEN-1-OL Diniconazole trans-2-Hexenoic acid Docetaxel trans-2-Hexenyl acetate 1-Hexene TRANS-2-HEXEN-1-OL TRANS-2-DODECEN-1-OL TRANS-3-HEXEN-1-OL,TRANS-3-HEXEN-1-OL 98+%,trans-3-Hexen-1-ol,97% trans-2-Octen-1-ol trans-2-Hexen-1-ol TRANS-2-HEPTEN-1-OL trans,trans-2,4-Undecadienal Allylestrenol rich_d_transallethrin TRANS,TRANS-2,4-HEXADIEN-1-OL trans-2-Nonen-1-ol TRANS-2-UNDECEN-1-OL

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