TRIPHENYLGERMANE

TRIPHENYLGERMANE Basic information

Product Name:	TRIPHENYLGERMANE
Synonyms:	GERMANIUM TRIPHENYL;TRIPHENYLGERMANIUM HYDRIDE;TRIPHENYLGERMANE;TRIPHENYL GERMANIUM;Triphenylgermanyl hydride;Germane, triphenyl-;TRIPHENYLGERMANE ISO 9001：2015 REACH
CAS:	2816-43-5
MF:	C18H16Ge
MW:	304.96
EINECS:	220-569-0
Product Categories:	Chemical Synthesis;CVD and ALD Precursors by Metal;Germanium;Materials Science;Metal Hydrides;Micro/NanoElectronics;GermaniumSynthetic Reagents;Metal HydridesOrganometallic Reagents;Organogermanium;Others;Precursors by Metal;Organometallic Reagents;Synthetic Reagents;Vapor Deposition Precursors;Reduction;Vapor Deposition Precursors
Mol File:	2816-43-5.mol

TRIPHENYLGERMANE Chemical Properties

Melting point	40-43 °C (lit.)
Boiling point	128-9°C 0,03mm
refractive index	1.6187
Fp	>110°C
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	36
WGK Germany	3
TSCA	No

MSDS Information

Provider	Language
SigmaAldrich	English

TRIPHENYLGERMANE Usage And Synthesis

Uses	It may be used in the isomerization of (Z) alkene.1 TEMPO (2,2,6,6-Tetramethylpiperidinyloxy) reacts with triphenylgermanium hydride to form its corresponding germyl radical. 2
Application	Readily adds to terminal acetylenes and olefins. Used in the reductive alkylation of acrylonitrile and enones.
General Description	Triphenylgermanium hydride is a hydrogen donor.

TRIPHENYLGERMANE Preparation Products And Raw materials

Raw materials	2,4,6-TRI-TERT-BUTYLNITROSOBENZENE-->TETRAPHENYLGERMANE-->DIPOTASSIUM TRIS(1,2-BENZENEDIOLATO-O,O')GERMANATE-->HEXAPHENYLDIGERMANE-->Lithium Aluminum Hydride
Preparation Products	9-Fluorenol-->TRIPHENYLGERMANIUM CHLORIDE-->Vanadinocene Dichloride

TRIS(PENTAFLUOROPHENYL)GERMANETIOL BIS[TRIS(PENTAFLUOROPHENYL)GERMIL]SELENIDE TRIPHENYLGERMANIUM CHLORIDE TRIS(PENTAFLUOROPHENYL)GERMANESELENOL (p-Dimethylaminophenyl)triphenylgermane TRIS(PENTAFLUOROMETHYL)GERMANE [β-(Allyloxy)phenethyl]triphenylgermane TRIS(PENTAFLUOROPHENYL)GERMANIUM BROMIDE (Pentafluorophenyloxy)triphenylgermane TETRAKIS(PENTAFLUOROPHENYL)GERMANE [(E)-1-Dodecenyl]triphenylgermane HEXAPHENYLDIGERMANE TETRAPHENYLGERMANE TRIPHENYLGERMANE TRIS(PENTAFLUOROPHENYL)GERMYLTRIS(PENTAFLUOROPHENYL)STANNYLSELENIDE HEXAPHENYLDIGERMOXANE [(Z)-1-Dodecenyl]triphenylgermane HEXAKIS(PENTAFLUOROPHENYL)DIGERMANE

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