TRANS-1,3-PENTADIENE

TRANS-1,3-PENTADIENE Basic information
Product Name:TRANS-1,3-PENTADIENE
Synonyms:1-Methylbutadiene;CH2=CHCH=CHCH3;Penta-1,3-diene;Pentadiene-1,3;piperylene,60%cisandtransisomers;Rcra waste number U186;rcrawastenumberu186;l,3-Pentadiene
CAS:504-60-9
MF:C5H8
MW:68.12
EINECS:207-995-2
Product Categories:
Mol File:504-60-9.mol
TRANS-1,3-PENTADIENE Structure
TRANS-1,3-PENTADIENE Chemical Properties
Melting point −87 °C(lit.)
Boiling point 42 °C(lit.)
density 0.683 g/mL at 25 °C(lit.)
vapor density 2.4 (vs air)
vapor pressure 6.56 psi ( 20 °C)
refractive index n20/D 1.433(lit.)
Fp <−30 °F
storage temp. Refrigerator
Stability:Stable. Incompatible with strong oxidizing agents. Very flammable - note low flash point and low boiling point.
CAS DataBase Reference504-60-9(CAS DataBase Reference)
EPA Substance Registry System1,3-Pentadiene (504-60-9)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-65
Safety Statements 16-23-26-36-62-24/25
RIDADR UN 3295 3/PG 2
WGK Germany 3
RTECS RZ2465000
HazardClass 3.1
PackingGroup I
Hazardous Substances Data504-60-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
TRANS-1,3-PENTADIENE Usage And Synthesis
Chemical Propertiescolourless liquid
DefinitionChEBI: (E)-1,3-pentadiene is an alkadiene consisting of pentane with the two double bonds located at positions 1 and 3.
General DescriptionA clear colorless liquid with an acrid odor. Flash point of -20°F. Boiling point 5°F. A dangerous fire risk. Vapors are irritating to the eyes and respiratory system. Subject to polymerization if heated or contaminated. If the polymerization takes place inside a container, the container may violently rupture. Insoluble in water. Used to make intermediates and polymers.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileTRANS-1,3-PENTADIENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides. Violent explosions at low temperatures in ammonia synthesis units have been traced to the addition products of dienes and nitrogen dioxide [Bretherick, 5th Ed., 1995].
Health HazardVapors may cause dizziness or suffocation; contact may irritate skin and eyes.
3-Hydroxy-1,4-pentadiene 2,4-Dimethyl-2,4-pentadiene,2,4-DIMETHYL-1,3-PENTADIENE 98% 1,5-Bis-(2-furanyl)-1,4-pentadiene-3-one 4-METHYL-1,3-PENTADIENE 98% 1,3,5-Triphenyl-1,2,4,5-tetraaza-1,3-pentadiene 4,7-Methano-1H-indene, 3a,4,7,7a-tetrahydro-, polymer with 2-methyl-2-butene and 1,3-pentadiene 1,1-Dichloro-4-methyl-1,3-pentadiene 2,4-Bis(trimethylsilyloxy)-3-methylthio-1,3-pentadiene 3-METHYL-1,4-PENTADIENE 99+% 1,1,3-Tris(trimethylsilyl)-1,2-pentadiene 3-Vinyl-1,4-pentadiene,3-Ethenyl-1,4-pentadiene N-(5-Anilino-2,4-pentadiene-1-ylidene)aniline,N-Phenyl-5-(phenylimino)-1,3-pentadiene-1-amine cis-1,3-Pentadiene (stabilized with TBC) PIPERYLENE/BUTENE/PENTENE/PENTADIENE COPOLYMER (2Z,4Z)-1-Piperidino-5-(1,3-benzodioxole-5-yl)-2,4-pentadiene-1-one 1,5-Bis[(4-nitrophenyl)thio]-2,4-diphenyl-1,3,5-triaza-2,4-pentadiene 1,2-PENTADIENE 2-methyl-trans-1,3-pentadien

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