(1R)-(-)-Nopol

(1R)-(-)-Nopol Basic information
Product Name:(1R)-(-)-Nopol
Synonyms:(1R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL;Dimethylbicyclohepteneethanol;(1R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ethanol;6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL;6,6-DIMETHYL-2-NORPINENE-2-ETHANOL;Bicyclo3.1.1hept-2-ene-2-ethanol, 6,6-dimethyl-, (1R,5S)-;(-)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol;(1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol
CAS:35836-73-8
MF:C11H18O
MW:166.26
EINECS:252-744-2
Product Categories:
Mol File:35836-73-8.mol
(1R)-(-)-Nopol Structure
(1R)-(-)-Nopol Chemical Properties
Boiling point 235-236 °C(lit.)
density 0.973 g/mL at 25 °C(lit.)
vapor pressure 2.17Pa at 20℃
refractive index n20/D 1.493
Fp 210 °F
storage temp. Refrigerator, under inert atmosphere
solubility Chloroform (Slightly), Methanol (Slightly)
pka15.03±0.10(Predicted)
form Oil
color Clear Colourless
optical activity[α]24/D 37°, neat
Water Solubility 333.5mg/L at 20℃
Merck 14,6683
BRN 3196379
LogP3.09 at 30℃
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS RC8870000
HS Code 29061900
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
(1R)-(-)-Nopol Usage And Synthesis
Chemical PropertiesClear colorless to light yellow liquid
Uses(-)-Nopol, is a chiral building block used in chemical synthesis. It is an intermediate that can be used for the synthesis of bulky moiety-modified analogs to the sandalwood odorant Polysantol.
DefinitionChEBI: (-)-Nopol is a monoterpenoid.
Application(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization.
General Description(1R)-(-)-Nopol is a chiral terpenol derivative.
(1R)-(-)-Nopol Preparation Products And Raw materials
Preparation ProductsBicyclo[3.1.1]heptan-3-one, 6,6-dimethyl-2-methylene-, (1R,5R)--->(1R)-(-)-NOPOL BENZYL ETHER
6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL (1R)-(+)-ALPHA-PINENE (1S)-(-)-alpha-Pinene ALPHA-PINENE (1S)-(-)-6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL (1R)-(-)-NOPYL ACETATE (1R)-(-)-Nopol (1R)-(-)-NOPOL BENZYL ETHER

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