Phenylethyl Anthranilate

Phenylethyl Anthranilate Basic information
Product Name:Phenylethyl Anthranilate
Synonyms:2-amino-benzoicaci2-phenylethylester;2-Phenylethyl 2-aminobenzoate;2-Phenylethyl o-aminobenzoate;2-phenylethyl-o-aminobenzoate;Anthranilic acid, phenethyl ester;anthranilicacid,phenethylester;Benzoic acid, 2-amino-, 2-phenylethyl ester;Benzoicacid,2-amino-,2-phenylethylester
CAS:133-18-6
MF:C15H15NO2
MW:241.29
EINECS:205-098-0
Product Categories:
Mol File:133-18-6.mol
Phenylethyl Anthranilate Structure
Phenylethyl Anthranilate Chemical Properties
Melting point 39-44 °C(lit.)
Boiling point 226 °C(lit.)
density 1.0944 (rough estimate)
FEMA 2859 | PHENYLETHYL ANTHRANILATE
refractive index 1.5200 (estimate)
Fp >230 °F
pka2.16±0.10(Predicted)
color White to yellow crystals
Odorgrape odor
Odor Typefloral
JECFA Number1543
LogP4.06
EPA Substance Registry System2-Phenylethyl anthranilate (133-18-6)
Safety Information
Hazard Codes Xi,N
Risk Statements 36/37/38-50/53
Safety Statements 26-37/39-60-61
RIDADR UN 3077 9/PG 3
WGK Germany 2
RTECS CB3720000
Toxicityskn-rbt 500 mg/24H MOD FCTXAV 14,659,76
MSDS Information
ProviderLanguage
SigmaAldrich English
Phenylethyl Anthranilate Usage And Synthesis
Chemical PropertiesPure phenethyl anthranilate is almost odorless. With other materials, it has a characteristic odor reminiscent of neroli and grapefruit odor with a sweet, grape and orange undertone. It has low stablility.
OccurrenceHas apparently not been reported to occur in nature.
UsesPhenylethyl Anthranilate is a synthetic flavoring agent that is a stable, white to yellow crystal of grape and orange blossom odor. It should be stored in glass or polyethylene-lined containers. It is used for flavors such as grape and cherry in applications such as beverages, ice cream, candy, and baked goods at 2–6 ppm.
DefinitionChEBI: 2-Phenylethyl 2-aminobenzoate is a benzoate ester.
PreparationBy direct esterification of anthranilic acid with phenylethyl alcohol; pure material from phenylethyl alcohol plus isatoic anhydride; also from phenylethyl alcohol and methylanthranilate.
General DescriptionColorless solid with an odor of grape and orange. Insoluble in water.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileFEMA 2859 forms salts readily with acids. Hydrolyzes under alkaline pH conditions. .
Fire HazardFlash point data are not available for FEMA 2859, but FEMA 2859 is probably combustible.
Safety ProfileA skin irritant. See also ESTERS. When heated to decomposition it emits toxic fumes of NOx.
Phenylethyl Anthranilate Preparation Products And Raw materials
Raw materialsAnthranilic acid-->Phenethyl alcohol
2-(3,4-DICHLOROPHENYL)-2-OXOETHYL 2-AZIDOBENZOATE SALOR-INT L210080-1EA SALOR-INT L210064-1EA 2-(4-CHLOROPHENYL)-2-OXOETHYL 2-AZIDOBENZOATE Tritoqualine SALOR-INT L210099-1EA 2-[1,1'-BIPHENYL]-4-YL-2-OXOETHYL 2-AZIDOBENZOATE SALOR-INT L210048-1EA 2-AMINO-BENZOIC ACID 2-BIPHENYL-4-YL-2-OXO-ETHYL ESTER SALOR-INT L210072-1EA 2-AMINO-BENZOIC ACID 2-(3,4-DIMETHOXY-PHENYL)-2-OXO-ETHYL ESTER 2-AMINO-BENZOIC ACID 2-(2,3-DIHYDRO-BENZO[1,4]DIOXIN-6-YL)-2-OXO-ETHYL ESTER Phenylethyl Anthranilate 2-OXO-2-PHENYLETHYL 2-AMINO-3,5-DICHLOROBENZENECARBOXYLATE 458L 2-AMINO-BENZOIC ACID 2-OXO-2-PHENYL-ETHYL ESTER SALOR-INT L210056-1EA 2-(4-FLUOROPHENYL)-2-OXOETHYL 2-AZIDOBENZOATE

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