BENZENE CHROMIUM TRICARBONYL

BENZENE CHROMIUM TRICARBONYL Basic information

Product Name:	BENZENE CHROMIUM TRICARBONYL
Synonyms:	(6-Benzene)tricarbonylchromium;(benzene)tricarbonyl-chromiu;(eta(sup6)-benzene)tricarbonyl-chromiu;(η6-benzene)tricarbonylchromium;Benchrotrene;Benzene-chromium carbonyl complex;Benzenechromotricarbonyl;Benzentrikarbonylchromium
CAS:	12082-08-5
MF:	C9H6CrO36*
MW:	214.14
EINECS:	235-146-6
Product Categories:	metal carbonyl complexes
Mol File:	12082-08-5.mol

BENZENE CHROMIUM TRICARBONYL Chemical Properties

Safety Information

MSDS Information

BENZENE CHROMIUM TRICARBONYL Usage And Synthesis

Chemical Properties	yellow crystalline powder
Uses	Catalyst for: Oxidation of alkenes Hydrogenation of alkynes
Purification Methods	Purify the complex by sublimation in vacuo. A possible impurity is 2-picoline which can be removed by washing with pentane and drying. It is then purified further by sublimation at 80-85o/10-3mm, or by recrystallisation from Et2O to give yellow crystals. 1H NMR in CDCl3 should give a single peak at 4.68. [Rausch J Org Chem 39 1787 1974, Pauson in Houben-Weyl Meth Org Chem V, E 18 Pt I p226 Theme Verlag, Stuttgart 1986, Beilstein 5 IV 625.]

BENZENE CHROMIUM TRICARBONYL Preparation Products And Raw materials

Raw materials

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