ALLYLDIPHENYLPHOSPHINE

ALLYLDIPHENYLPHOSPHINE Basic information
Product Name:ALLYLDIPHENYLPHOSPHINE
Synonyms:Phosphine,diphenyl-2-propen-1-yl-;NSC 180819;NSC 616248;ALLYLDIPHENYLPHOSPHINE, TECH., 80%;2-Propenyldiphenylphosphine;Allyldiphenylphosphine,80%,tech.;Diphenylphosphino;DIPHENYL-2-PROPENYLPHOSPHINE
CAS:2741-38-0
MF:C15H15P
MW:226.25
EINECS:626-057-7
Product Categories:Achiral Phosphine;Aryl Phosphine;Ligand
Mol File:2741-38-0.mol
ALLYLDIPHENYLPHOSPHINE Structure
ALLYLDIPHENYLPHOSPHINE Chemical Properties
Boiling point 194-200 °C/15 mmHg (lit.)
density 1.049 g/mL at 25 °C (lit.)
refractive index n20/D 1.619(lit.)
Fp >230 °F
form Liquid
color Colorless
Water Solubility Soluble in most organic solvents. Insoluble in water.
Sensitive Air Sensitive
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-27-28-36/37/39-39-37-36
RIDADR UN3278
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
ALLYLDIPHENYLPHOSPHINE Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
UsesCocatalyst in palladium catalyzed hydrocarboxylation reactions. Cocatalyst in Palladium catalyzed cross-coupling reactions. Ligand for hydroformylation catalysts. Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions. Catalyst precursor for alkene hydroboration.
UsesAllyldiphenylphosphine is used as a cocatalyst in palladium catalyzed hydrocarboxylation reactions, cocatalyst in Palladium catalyzed cross-coupling reactions, ligand for hydroformylation catalysts, ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions, catalyst precursor for alkene hydroboration.
Uses
  • Cocatalyst in palladium catalyzed hydrocarboxylation reactions
  • Cocatalyst in Palladium catalyzed cross-coupling reactions
  • Ligand for hydroformylation catalysts
  • Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions
  • Catalyst precursor for alkene hydroboration
ALLYLDIPHENYLPHOSPHINE Preparation Products And Raw materials
ALLYLDIPHENYLPHOSPHINE OXIDE CROTYL TRIPHENYLPHOSPHONIUM BROMIDE 2-METHYLALLYL TRIPHENYLPHOSPHONIUM CHLORIDE METHYL 4-(TRIPHENYLPHOSPHONIO)CROTONATE BROMIDE 1-(DIPHENYLPHOSPHORYL)-3-PHENYLPROP-2-EN-1-OL 2-BUTENE-1,4-BIS(TRIPHENYLPHOSPHONIUM CHLORIDE) AURORA KA-1138 (e,e)-2,4-Heptadienyldiphenylphosphine Oxide (3,3-DIMETHYLALLYL)TRIPHENYLPHOSPHONIUM BROMIDE 2-BUTENYLENEBIS(TRIPHENYLPHOSPHONIUM) DIBROMIDE (2-BUTENYL)TRIPHENYLPHOSPHONIUM CHLORIDE Allyltriphenylphosphonium bromide Geranyltriphenylphosphoniumbromide ALLYLDIPHENYLPHOSPHINE (4-BROMO-2-BUTENYL)TRIPHENYLPHOSPHONIUM BROMIDE Allyl triphenylphosphonium chloride CINNAMYLTRIPHENYLPHOSPHONIUM CHLORIDE PHOSPHINE OXIDE, [2-[3,5-BIS [[(1,1-DIMETHYLETHYL) DIMETHYLSILY]OXY]-2-METHYLENECYCLOHEXYLIDENE]ETHYL]DIPHENYL-,[3S-(1Z,3A,5B0)]

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