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| | (1S,2S)-(+)-1,2-Diaminocyclohexane Basic information |
| Product Name: | (1S,2S)-(+)-1,2-Diaminocyclohexane | | Synonyms: | (1S,2S)-Cyclohexane-1,2-Diamin;(1S,2S)-(+)-1,2-Diaminocyclohexane,99%(S,S)-DACH;(1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE (S,S)-DACH;(1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE 98%;S-DACH;(+)-(S,S)-1,2-DIAMINOCYCLOHEXANE;(S,S)-(+)-1,2-DIAMINOCYCLOHEXANE;(S,S)-1,2-DIAMINOCYCLOHEXANE | | CAS: | 21436-03-3 | | MF: | C6H14N2 | | MW: | 114.19 | | EINECS: | | | Product Categories: | Chiral Nitrogen;DACH&Trost Series;Amines (Chiral);Chiral Building Blocks;Synthetic Organic Chemistry;organic amine;chiral;API intermediates;Chiral reagent;Chiral Compound | | Mol File: | 21436-03-3.mol |  |
| | (1S,2S)-(+)-1,2-Diaminocyclohexane Chemical Properties |
| Melting point | 40-43 °C (lit.) | | alpha | 25.25 º (589nm, c=5, 1 M HCl) | | Boiling point | 104-110 °C/40 mmHg (lit.) | | density | 0.951 | | refractive index | 1.4886 | | Fp | 169 °F | | storage temp. | Keep in dark place,Inert atmosphere,2-8°C | | form | Crystals or Powder | | pka | 10.76±0.70(Predicted) | | color | White to light beige | | optical activity | [α]20/D +25°, c = 5 in 1 M HCl | | Water Solubility | soluble | | Sensitive | Air Sensitive | | BRN | 2801645 | | InChIKey | SSJXIUAHEKJCMH-WDSKDSINSA-N | | CAS DataBase Reference | 21436-03-3(CAS DataBase Reference) | | NIST Chemistry Reference | (1S,2S)-(+)-1,2-Diaminocyclohexane(21436-03-3) |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3259 8/PG 3 | | WGK Germany | 3 | | F | 10-34 | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29213000 |
| | (1S,2S)-(+)-1,2-Diaminocyclohexane Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powder | | Uses | suzuki reaction | | Uses | For synthesis of optically active products | | Uses | Versatile ligand for the formation of metal complexes. Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis. | | Purification Methods | Distil or recrystallise the diamine from pet ether under N2 or Ar. Store it as above. The 1S,2S-base D-tartrate salt has M 264.3, m 180 -1 8 4o(dec) and [] 25 -12.5o (c 4, H2O) from which the free base can be purified or optically enriched. It is a useful chiral synthon. [Fjii et al. J Chem Soc, Chem Commun 45 1985, Takahashi et al. Tetrahedron Lett 30 7095 1989, Hanassian et al. J Org Chem 58 1991 1993, Beilstein 13 III 7.] |
| | (1S,2S)-(+)-1,2-Diaminocyclohexane Preparation Products And Raw materials |
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