3-Bromo-4-methylaniline

3-Bromo-4-methylaniline Basic information
Product Name:3-Bromo-4-methylaniline
Synonyms:3-BROMO-4-METHYLANILINE;3-BROMO-P-TOLUIDINE;3-BROMO-PARA-TOLUIDINE;3-Bromo-4-methyl-1-benzenamine;3-Bromo-4-methylbenzen-1-amine;3-Bromo-4-methylaniline,97%;3-Bromo-4-methylbenzenamine;8CI.4-Amino-2-bromotolueneCh
CAS:7745-91-7
MF:C7H8BrN
MW:186.05
EINECS:231-807-8
Product Categories:Anilines, Amides & Amines;Bromine Compounds;Building Blocks;C7;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Anilines, Aromatic Amines and Nitro Compounds;Amines;Aromatics
Mol File:7745-91-7.mol
3-Bromo-4-methylaniline Structure
3-Bromo-4-methylaniline Chemical Properties
Melting point 27-30 °C (lit.)
Boiling point 254-257 °C (lit.)
density 1.4700 (rough estimate)
refractive index 1.611-1.613
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO, Methanol
pka3.96±0.10(Predicted)
form Liquid After Melting
color Clear yellow to red-brown
Water Solubility Insoluble in water.
BRN 1562057
InChIKeyGRXMMIBZRMKADT-UHFFFAOYSA-N
CAS DataBase Reference7745-91-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzenamine, 3-bromo-4-methyl-(7745-91-7)
Safety Information
Hazard Codes T
Risk Statements 25-36/37/38
Safety Statements 26-45-37/39-28A
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
RTECS XU4375000
Hazard Note Toxic
HazardClass 6.1
PackingGroup III
HS Code 29214300
MSDS Information
ProviderLanguage
3-Bromo-p-toluidine English
SigmaAldrich English
ACROS English
ALFA English
3-Bromo-4-methylaniline Usage And Synthesis
Chemical Propertiesclear yellow to red-brown liquid after melting
Uses3-Bromo-4-methylaniline may be used in the synthesis of 1,7-dihalo Tr?ger′s base isomers. It is suitable for use to investigate the reactions of distonic 4-(N,N,N-trimethylammonium)-2-methylphenyl and 5-(N,N,N-trimethylammonium)-2-methylphenyl radical cations with O2 by ion-trap mass spectrometry.
Uses3-Bromo-4-methylaniline is used in the synthesis of 1,7-dihalo Tr?ger?s base isomers. It is suitable for use to investigate the reactions of distonic 4-(N,N,N-trimethylammonium)-2-methylphenyl and 5-(N,N,N-trimethylammonium)-2-methylphenyl radical cations with O2 by ion-trap mass spectrometry.
3-Bromo-4-methylaniline Preparation Products And Raw materials
Preparation Products2-Bromo-4-chlorotoluene-->2-AMINO-6-BROMO-5-METHYLBENZOIC ACID-->2-Bromo-4-fluorotoluene-->3-Bromo-4-methylbenzenesulphonamide-->4-Bromo-5-methyl-2,3-indolinedione-->2-Bromo-4-methylbenzaldehyde-->(3-BroMo-4-Methyl-phenyl)-carbaMic acid tert-butyl ester-->1,3-Benzenedicarbonitrile, 4-formyl- (9CI)
3-Bromo-2-methylaniline, HCl 2-BROMO-4-METHYLANILINE, (4-AMINO-3-BROMOTOLUENE; 2-BROMO-P-TOLUID N-(1H-1,2,3-BENZOTRIAZOL-1-YLMETHYL)-4-BROMO-3-METHYLANILINE SALOR-INT L169846-1EA 4-Bromo-3-methylaniline hydrochloride 2-[(3-BROMO-4-METHYLANILINO)METHYL]BENZENOL 4-Bromo-5-methyl-2,3-indolinedione 2,4-Dibromo-6-methylaniline 3,3',5,5'-Tetramethylbenzidine dihydrochloride 5-BROMO-3,4-DIMETHYLBENZENE-1,2-DIAMINE 6-BROMO-5-METHYLISATIN N-(TERT-BUTOXYCARBONYL)-4-BROMO-2-METHYLANILINE toluidine 5-(2-BROMO-4-NITRO-PHENYL)-FURAN-2-CARBALDEHYDE 2-BROMO-4-NITROBENZOIC ACID 4-BROMO-O-TOLUIDINE (NH2=1) = 4-BROMO-2-METHYLANILINE 1-BROMO-2,4-DIMETHYL-5-NITROBENZENE 3-Bromo-5-methylaniline, HCl

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