2-Iodosobenzoic acid

2-Iodosobenzoic acid Basic information
Product Name:2-Iodosobenzoic acid
Synonyms:2-iodosyl-benzoicaci;2-iodosylbenzoicacid;o-iodoso-benzoicaci;o-iodosylbenzoicacid;1-HYDROXY-1,2-BENZIODOXOL-3(1H)-ONE;2-IODOSOBENZOIC ACID;O-IODOSOBENZOIC ACID;2-iodosobenzoic acid moistened with water (H2O ~10%)
CAS:304-91-6
MF:C7H5IO3
MW:264.02
EINECS:206-159-4
Product Categories:Hypervalent Iodine Compounds;Oxidation;Synthetic Organic Chemistry;Reagents for Chemical Cleavage of Proteins;Enzymatic and Chemical Protein Cleavage;Mass Spectrometry;proteinmod
Mol File:304-91-6.mol
2-Iodosobenzoic acid Structure
2-Iodosobenzoic acid Chemical Properties
Melting point 230 °C (dec.)(lit.)
storage temp. −20°C
form Powder
pka2.84±0.36(Predicted)
color White to off-white
Water Solubility Insoluble in water.
Sensitive Light Sensitive
BRN 1939973
CAS DataBase Reference304-91-6(CAS DataBase Reference)
EPA Substance Registry System2-Iodosylbenzoic acid (304-91-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS DH3056550
8-23
Hazard Note Irritant
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-Iodosobenzoic acid Usage And Synthesis
Chemical PropertiesWhite powder
Uses1-Organosulfonyloxy-1, 2-benziodoxol-3-(1H)-ones (3, 4, 5) can be prepared in one step from 2-iodosobenzoic acid and the corresponding sulfonic acids. 2-carboxydiphenyliodonium salts was prepared by the acid-catalyzed condensation of 2-iodosobenzoic acid with benzene, mesitylene, and cyclohexylbenzene.
DefinitionChEBI: A benzoic acid compound having an iodosyl substituent at the ortho-position.
Purification MethodsCrystallise the acid from EtOH and dry it in vacuo.[Beilstein 9 H 363.]
2-Iodosobenzoic acid Preparation Products And Raw materials
FERROUS SULFATE 2-Acetylbenzoic acid 4-Methyl-2-iodosobenzoic acid 4-Iodosobenzoic acid 2-Iodobenzoic acid 4-Pentyl-2-iodosobenzoic acid 4-Octyl-2-iodosobenzoic acid 4-Ethyl-2-iodosobenzoic acid 2-Iodoxybenzoic acid Ascoric Acid O-IODOSOBENZOIC ACID, SODIUM SALT Methyl 2-iodobenzoate 1-HYDROXY-1,3-DIOXO-1,3-DIHYDRO-1L5-BENZO[D][1,2]IODOXOLE-4-CARBOXYLIC ACID Sodium lauroylglutamate 2-Iodosobenzoic acid 4-Propyl-2-iodosobenzoic acid BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER Citric acid

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