Lithium bis(trifluoromethanesulphonyl)imide

Lithium bis(trifluoromethanesulphonyl)imide Basic information
Product Name:Lithium bis(trifluoromethanesulphonyl)imide
Synonyms:bis(Trifluoromethanesulphonyl)imide, lithium salt;Bis(trifluoromethane)sulfonimide lithium salt, 99.95% metals basis;Lithium bis(trifluoromethylsulfonyl)imide, 98+%;Lithium bis(trifluoromethanesulphonyl)imide 99%;Lithiumbis(trifluoromethanesulphonyl)imide99%;1,1,1-Trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfon amide lithium salt;Bis(trifluoromethylsulfonyl)amine lithium salt, Lithium bistrifluoromethanesulfonimidate;BIS(TRIFLUOROMETHYLSULFONYL)AMINE LITHIUM SALT
CAS:90076-65-6
MF:C2F6LiNO4S2
MW:287.09
EINECS:415-300-0
Product Categories:Metal Triflates;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Li (Lithium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Organic lithium battery electrolyte lithium salt;bc0001;90076-65-6
Mol File:90076-65-6.mol
Lithium bis(trifluoromethanesulphonyl)imide Structure
Lithium bis(trifluoromethanesulphonyl)imide Chemical Properties
Melting point 234-238 °C(lit.)
density 1,334 g/cm3
vapor pressure 0Pa at 25℃
Fp >100°C (>212°F)
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 10 mg/mL, clear, colorless
form Hygroscopic Powder
Specific Gravity1.334
color White
Water Solubility Soluble in water.
Sensitive Moisture Sensitive
BRN 6625414
InChIKeyQSZMZKBZAYQGRS-UHFFFAOYSA-N
LogP-1.46
CAS DataBase Reference90076-65-6(CAS DataBase Reference)
EPA Substance Registry SystemMethanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-, lithium salt (90076-65-6)
Boiling point 234-238?°C (lit.)
Safety Information
Hazard Codes T,C
Risk Statements 24/25-34-52/53-48/22
Safety Statements 22-26-36/37/39-45-61
RIDADR UN 2923 8/PG 2
WGK Germany 2
Hazard Note Harmful/Corrosive/Moisture Sensitive
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Lithium bis(trifluoromethanesulphonyl)imide Usage And Synthesis
DescriptionLithium bis(trifluoromethylsulphonyl)imide (LiTFSI) is normally used as a p-dopant?to enhance the conductivity and hole mobility of the?Spiro-OMeTAD for perovskite solar cells. It is believed that The function of LiTFSI in PSCs is?similar to that in solid-state dye-sensitised solar cells [2].
Chemical PropertiesWhite hygroscopic powder
UsesLithium bis(trifluoromethylsulfonyl)imide is used in the preparation of chiral imidazolium salt through an anion metathesis of the corresponding triflate organic electrolyte-based lithium batteries. It finds application in the preparation of rare-earth Lewis acid catalysts. It is also useful in primary and secondary lithium cells using organic liquid electrolytes and polymer batteries.
General DescriptionBis(trifluoromethane)sulfonimide lithium salt is a synthetic reagent.
Flammability and ExplosibilityNonflammable
Lithium bis(trifluoromethanesulphonyl)imide Preparation Products And Raw materials
Preparation Products1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE-->1-BUTYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOR-->TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE-->1-BUTYL-3-METHYLPYRIDINIUM BIS(TRIFLUORM-->1-DODECYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE-->ETHYL-DIMETHYL-PROPYLAMMONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE-->TETRAMETHYLAMMONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE-->1,2-Dimethyl-3-octyl-1H-imidazolium salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
O-Phthalimide Bismaleimide TRIFLUOROMETHANESULFONYL CHLORIDE Succinimide TRIFLUOROMETHANESULFONAMIDE DIALIFOS Lithium amide Methanesulfonyl chloride Lithium bis(trifluoromethanesulphonyl)imide Maleimide Aniline Bis(2-ethylhexyl)amine Lithium Aluminum Hydride Trifluoromethane TRIFLUOROMETHANESULFONIMIDE METHANE Lithium Lithium chloride

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