ALLYL PHENYLACETATE

ALLYL PHENYLACETATE Basic information
Product Name:ALLYL PHENYLACETATE
Synonyms:phenyl-aceticaciallylester;PHENYLACETIC ACID ALLYL ESTER;ALLYL PHENYLACETATE 99+%;Benzeneacetic acid allyl ester;Phenylacetic acid 2-propenyl ester;2-phenylacetic acid allyl ester;prop-2-enyl 2-phenylacetate;prop-2-enyl 2-phenylethanoate
CAS:1797-74-6
MF:C11H12O2
MW:176.21
EINECS:217-281-2
Product Categories:A-B;Alphabetical Listings;Flavors and Fragrances
Mol File:1797-74-6.mol
ALLYL PHENYLACETATE Structure
ALLYL PHENYLACETATE Chemical Properties
Boiling point 239-240 °C(lit.)
density 1.037 g/mL at 25 °C(lit.)
FEMA 2039 | ALLYL PHENYLACETATE
refractive index n20/D 1.508(lit.)
Fp >230 °F
form clear liquid
color A colourless slightly viscous liquid.
Odorat 100.00 %. honey fruity rum
Odor Typehoney
JECFA Number17
LogP2.81
CAS DataBase Reference1797-74-6(CAS DataBase Reference)
EPA Substance Registry SystemBenzeneacetic acid, 2-propenyl ester (1797-74-6)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS AJ2450000
HS Code 29163990
toxicityThe acute oral LD50 value in rats was reported as 0.65 g/kg and the acute dermal LD50 value in rabbits as >0.31 g/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ALLYL PHENYLACETATE Usage And Synthesis
Chemical PropertiesA colorless liquid with sweet honey-like, but faint odor and sweet fruity undertones.
OccurrenceHas apparently not been reported to occur in nature
UsesAllyl Phenylacetate is a synthetic flavoring agent that is a stable, colorless to light yellow liquid with a fruity odor of banana and honey. it should be stored in glass or tin containers. it is used in flavors for honey and has application in candy and baked goods at 10–15 ppm.
PreparationBy direct esterification in benzene solution
DefinitionChEBI: 2-Propenyl phenylacetate is a member of benzenes.
Synthesis Reference(s)Synthesis, p. 112, 1991 DOI: 10.1055/s-1991-26391
Safety ProfileModeratelv toxic by ingestion. A human sktn irritan;. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS and ALLYL COMPOUNDS.
MetabolismIn the rat, allyl acetate and allyl alcohol are metabolized to 3-hydroxypropylmercapturic acid, which is excreted in the urine
ALLYL PHENYLACETATE Preparation Products And Raw materials
Raw materialsAllyl alcohol-->Phenylacetic acid
AURORA KA-5064 TINYATOXIN DIPHENYLACETIC ACID, (2,3-DIHYDRO-5-OXO-(1H,5H)-BENZO[IJ]QUINOLIZIN-6-YL)METHYL ESTER AURORA KA-5493 LINALYL PHENYL ACETATE Pulvinicanhydride PPAHV AURORA KA-5065 PHENYLACETIC ACID TRANS-2-HEXEN-1-YL ESTER GERANYL PHENYLACETATE PDDHV CINNAMYL PHENYL ACETATE PDNHV RESINIFERATOXIN VETIVERYL PHENYLACETATE 12-Deoxyphorbol-13-phenylacetate-20-(4-butoxyphenylacetate) RESINIFERATOXIN, [3H]- AURORA KA-5066

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