ChemicalBook Product Catalog Chemical Reagents Organic reagents Sulfone, sulfoxide compound PHENYL VINYL SULFOXIDE

PHENYL VINYL SULFOXIDE

PHENYL VINYL SULFOXIDE Basic information
Product Name:PHENYL VINYL SULFOXIDE
Synonyms:(Vinylsulfinyl)benzene;Sulfoxide, phenyl vinyl;PHENYL VINYL SULFOXIDE;phenyl vinyl sulphoxide;Benzene, (ethenylsulfinyl)-;NISTC20451530;VINYL PHENYL SULFOXIDE;(Ethenylsulfinyl)benzene
CAS:20451-53-0
MF:C8H8OS
MW:152.21
EINECS:243-831-6
Product Categories:Organic Building Blocks;Sulfoxides;Sulfur Compounds
Mol File:20451-53-0.mol
PHENYL VINYL SULFOXIDE Structure
PHENYL VINYL SULFOXIDE Chemical Properties
Boiling point 93-95 °C/0.2 mmHg (lit.)
density 1.139 g/mL at 25 °C (lit.)
refractive index n20/D 1.585(lit.)
Fp >230 °F
storage temp. 2-8°C
form liquid
color deeply yellow
BRN 2039218
Safety Information
Hazard Codes Xi
Risk Statements 41
Safety Statements 24/25-39-26
WGK Germany 3
HS Code 2930909899
MSDS Information
ProviderLanguage
SigmaAldrich English
PHENYL VINYL SULFOXIDE Usage And Synthesis
Synthesis Reference(s)The Journal of Organic Chemistry, 61, p. 2260, 1996 DOI: 10.1021/JO960178X
General DescriptionPhenyl vinyl sulfoxide reacts with lithium enolates of ketones at -78°C in THF to yield bicyclo[n.2.0]alkan-1-ols. It also reacts with in situ generated (dialkylamino)magnesium reagent to yield symmetrical β-(dialkylamino)dithioacetals. It participates as an acetylene equivalent in Diels-Alder reactions.
PHENYL VINYL SULFOXIDE Preparation Products And Raw materials
2-((4-(ISOPROPYL)PHENYL)SULFONYL)-3-(3-PHENOXYPHENYL)PROP-2-ENENITRILE 2-((4-METHYLPHENYL)SULFONYL)-3,3-DIMETHYLTHIOPROP-2-ENENITRILE 2-((4-METHYLPHENYL)SULFONYL)-3-(6-NITROBENZO[3,4-D]1,3-DIOXOLEN-5-YL)PROP-2-ENENITRILE SPECS AB-131/40647149 Phenyl vinyl sulfone 3-[(4-CHLORO-6-METHYLPYRIMIDIN-2-YL)AMINO]-2-[(4-CHLOROPHENYL)SULFONYL]ACRYLONITRILE TRANS-1,2-BIS(PHENYLSULFONYL)ETHYLENE PHENYL VINYL SULFOXIDE 3-((4-CHLOROPHENYL)SULFONYL)-4-ETHOXYBUT-3-EN-2-ONE 2-((4-CHLOROPHENYL)SULFONYL)-3-(PYRIMIDIN-2-YLAMINO)PROP-2-ENENITRILE THIANAPHTHENE-1,1-DIOXIDE LUCIFER YELLOW VS DILITHIUM SALT 2-((4-CHLOROPHENYL)SULFONYL)-3-ETHOXYPROP-2-ENENITRILE UNIBLUE A SODIUM SALT 3,3-DIMETHYLTHIO-2-(PHENYLSULFONYL)PROP-2-ENENITRILE 3-METHYLTHIO-3-(PHENYLAMINO)-2-(PHENYLSULFONYL)PROP-2-ENENITRILE P-TOLYL VINYL SULPHONE UNIBLUE A
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