COBALT(II) PHTHALOCYANINE

COBALT(II) PHTHALOCYANINE Basic information
Classification Applications
Product Name:COBALT(II) PHTHALOCYANINE
Synonyms:Cobalt phthalocyanin;Cobalt, (phthalocyaninato(2-))-;Cobalt, [29H,31H-phthalocyaninato(2-)-N(29)-,N(30)-,N(31)-,N(32)-]-, (SP-4-1)-;Cobalt,[29H,31H-phthalocyaninato(2(-))-N29,N30,N31,N32]-(SP-4-1;Cobaltous phthalocyanine;Phthalocyaninatocobalt(II);phthalocyanine cobalt(ii);Pigment blue 75 (C.I. 74160:2)
CAS:3317-67-7
MF:C32H16CoN8
MW:571.46
EINECS:222-012-7
Product Categories:Functional Materials;Phthalocyanines;Organometallics;Phthalonitriles & Naphthalonitriles;Transition Metal Compounds;oled materials;Classes of Metal Compounds;Co (Cobalt) Compounds;1
Mol File:3317-67-7.mol
COBALT(II) PHTHALOCYANINE Structure
COBALT(II) PHTHALOCYANINE Chemical Properties
Melting point >300 °C
density 0.677g/cm3
storage temp. Store at -20°C
solubility DMSO: < 1 mg/mL (insoluble or slightly soluble)
form crystal
color purple
Water Solubility Insoluble in water.
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 4121847
Stability:Stable. Incompatible with strong oxidizing agents.
LogP-1.1
EPA Substance Registry SystemCobalt, [29H,31H-phthalocyaninato(2-)-.kappa.N29,.kappa.N30,.kappa.N31,.kappa.N32]-, (SP-4-1)- (3317-67-7)
Safety Information
Hazard Codes Xn
Risk Statements 40
Safety Statements 36/37
WGK Germany 3
TSCA Yes
HS Code 29339900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
COBALT(II) PHTHALOCYANINE Usage And Synthesis
ClassificationPhthalocyanine salt, Hole-injection layer (HIL) materials, Light-Emitting Diodes, Organic electronics.
ApplicationsCobalt phthalocynine (CoPc) is a member of metal phthalocyanines (MPcs) are frequently used in many organic electronic devices such as light-emitting diodes (LEDs), organic photovoltaics (OPVs), organic field-effect transistors (OFETs) and chemical sensors as a p-type semiconducting material. Compared to other hole-injection layer (HIL) materials, most metal phthalocyanines are water and air stable, thermally stable, and nontoxic. They can be sublimed or sputtered with highly uniform, thin films on a variety of substrates. The synthesis of such materials are also relatively inexpensive and easy to prepare. The chemical structure of MPc allows tuning of its ionisation potential or HOMO levels by altering the central atom in Pc macrocycles.
Using cobalt phthalocyanine (CoPc) layer as a hole-injection layer (HIL), remarkable improvements in turn-on voltage and luminance have been observed in organic light-emitting diodes (OLED) [1, 2, 3, 4]. The driving voltages of the MPc electroluminance devices are found to decrease in the order of:
ZnPcwhich is in agreement with the order of HOMO levels of MPcs.

DescriptionCobalt phthalocynine (CoPc) is a member of metal phthalocyanines (MPcs) are frequently used in many?organic electronic devices such as light-emitting diodes (LEDs), organic photovoltaics (OPVs), organic field-effect transistors (OFETs) and chemical sensors ?as a p-type semiconducting material. Compared to other?hole-injection layer (HIL) materials, most metal phthalocyanines are water and air stable, thermally stable, and nontoxic.?They can be sublimed or sputtered with highly uniform, thin films on a variety of substrates. The synthesis of such materials are also relatively inexpensive and easy to prepare. The chemical structure of MPc allows tuning of its ionisation potential or?HOMO levels by altering the central atom in Pc macrocycles.
Chemical Propertiespowder
UsesCobalt(II) phthalocyanine may be used to develop carbon black based electrocatalysts. CoPC may be used as an end capping agent of a hyperbranched poly(aryl ether ketone) to be used for oxidative decomposition of 2,4,6,-trichlorophenol. CoPC modified carbon paste may be used as indicators for electrocatalytic amperometric measurements. ZnO impregnated with CoPC may be used as a sensitizer to determine the photodegradation of cyanide in aqueous suspension. CoPC catalyzed aerobic regenerations of aldehydes and ketones have been investigated.
General DescriptionCobalt(II) phthalocyanine (CoPC )is a metallopthalocyanine.
COBALT(II) PHTHALOCYANINE Preparation Products And Raw materials
Titanyl phthalocyanine N,N'-diphenyl-N,N'-di-p-tolyl- Benzidine N4,N4'-Di-1-naphthalenyl-N4,N4'-di-2-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine 9-bis[4-(N-naphthalen-1-yl-N-phenylamino)-phenyl]-9H-fluorene 4,4'-BIS[DI(3,5-XYLYL)AMINO]-4''-PHENYLTRIPHENYLAMINE Copper(II) phthalocyanine TPADPB 2,3-NAPHTHALOCYANINE COBALT(II) SALT (TETRA-T-BUTYLPHTHALOCYANINATO)COBALT(II) Phthalocyanine Cobalt(Ⅱ) phthalocyanine Sulfonated cobalt phthalocyanine SODIUM DICYANO(PHTHALOCYANINATO)COBALT(III)2.5-WATER (TETRACARBOXYPHTHALOCYANINATO)COBALT(II) COBALT(II) PHTHALOCYANINE (TETRAAMINOCHLOROPHTHALOCYANINATO)COBALT(II) Polyphthalocyanine catalyst COBALT(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-HEXADECAFLUORO-29H,31H-PHTHALOCYANINE

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