MELAMINE RESIN

MELAMINE RESIN Basic information
Product Name:MELAMINE RESIN
Synonyms:melamine,polymerwithformaldehyde;melamine20;melamine366;melamine-formaldehydecondensate;melamine-formaldehydecopolymer;melamine-formaldehydepolymer;melamine-formolcopolymer;melan125
CAS:9003-08-1
MF:C4H8N6O
MW:156.15
EINECS:
Product Categories:Polymers
Mol File:9003-08-1.mol
MELAMINE RESIN Structure
MELAMINE RESIN Chemical Properties
Melting point >330 °C (decomp)
density 1.13-1.14 g/cm3
storage temp. -20°C
form buffered aqueous solution
EPA Substance Registry SystemMelamine polymer with formaldehyde (9003-08-1)
Safety Information
MSDS Information
MELAMINE RESIN Usage And Synthesis
UsesMelamine formaldehyde is used for the treatment of heavy fabrics, draperies, coatings, collars, and apparel; in water- and oil-repellent and flame-retardant hrllsIies (effective on synthetic and natural fibers).
UsesSuggested starting dilutions are as follows: IHC-P: 1:100-1:1000, WB: 1:500-1:3000. Not yet tested in other applications. Optimal working dilutions should be determined experimentally by the end user.
DefinitionA type of amino resin made from melamine and formaldehyde. The first step in resin formation is the production of trimethylol melamine, C3N3(NHCH2OH)3, the molecules of which contain a ring with three carbon and three nitrogen atoms, the –NHCH2OH groups being attached to the carbon atoms. This molecule can combine further with others of the same kind by a condensation reaction. Excess formaldehyde or melamine can also react with trimethylol melamine or its polymers, providing many possibilities of chain growth and cross-linking. The nature and degree of polymerization depend upon pH, but heat is always needed for curing. Melamine resins are more waterand heat-resistant than urea resins. They may be water-soluble syrups (low molecular weight) or insoluble powders (high molecular weight) dispersible in water. Widely used as molding compounds with α-cellulose, wood flour, or mineral powders as fillers and with coloring materials; also for laminating, boil-proof adhesives, increasing wet strength of paper, textile treatment, leather processing, and for dinnerware and decorative plastic items. Butylated melamine resins are formed by incorporating butyl or other alcohols during resin formation, whereupon the –NHCH2OH groups convert to –NHCH2OC4H9. These resins are soluble in paint and enamel solvents and in surface coatings, often in combination with alkyds. They give exceptional curing speed, hardness, wear resistance, and resistance to solvents, soaps, and foods. Melamine-acrylic resins are water soluble and used for formation of water-base industrial and automotive finishes.
Preparation Melamine resin is a resin with melamine rings terminated with multiple hydroxyl groups derived from formaldehyde. This thermosetting plastic material is made from melamine and formaldehyde.
Industrial usesThis is a synthetic resin of the alkyd type madeby reacting melamine with formaldehyde. Theresin is thermosetting, colorless, odorless, andresistant to organic solvents. It is more resistantto alkalies and acids than urea resins, has betterheat and color stability, and is harder. Themelamine resins have the general uses of moldingplastics, and also are valued for dishes forhot foods or acid juices and they will not softenor warp when washed in hot water. Melamine,a trimer of cyanamide, has the composition(NC·NH2)3.
The melamine resins have good adhesivenessbut are too hard for use alone in coatingsand varnishes. They are combined with alcoholmodifiedurea-formaldehyde resins to give coatingmaterials of good color, gloss, flexibility, andchemical resistance. Urea-modified melamineformaldehyderesins are used for coatings andvarnishes. Melamine-formaldehyde moldingresin, with cellulose filler, has a tensile strengthof 51 MPa and dielectric strength per mil of12.8×106V/m.
Melamine-urea-formaldehyde resin with alignin extender is used as an adhesive for waterresistantplywood. Phenol-modified melamineformaldehyderesin solution is used for laminatingfibrous materials. Highly translucentmelamine-formaldehyde resin is used for moldinghigh-gloss buttons. Methylol-melamine,made by alkylating a melamine-formaldehyderesin with methyl alcohol, is used for shrinkproofingwoolen fabrics.
Biochem/physiol ActionsThis gene belongs to the subfamily of small cytokine CC genes. Cytokines are a family of secreted proteins involved in immunoregulatory and inflammatory processes. The CC cytokines are proteins characterized by two adjacent cysteines. The cytokine encoded by this gene displays chemotactic activity for resting CD4 or CD8 T cells and eosinophils. The product of this gene binds to chemokine receptors CCR3 and CCR10. This chemokine may play a role in the physiology of extracutaneous epithelial tissues, including diverse mucosal organs. [provided by RefSeq]
Aluminum acetylacetonate METHYL ISOCYANOACETATE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) N-BUTYLISOCYANIDE PHENYLSELENOL Tris(2,4-pentanedionato)chroMiuM(III) DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) SALCOMINE 2,4-PENTANEDIONE, SILVER DERIVATIVE 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE Tosylmethyl isocyanide COBALT(II) ACETYLACETONATE Cupric acetylacetonate Ethyl isocyanoacetate TERT-BUTYL ISOCYANIDE Ferric acetylacetonate COBALT ETHYLENE DIAMINE CHLORIDE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III)

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