Bis(triphenylphosphinepalladium) acetate

Bis(triphenylphosphinepalladium) acetate Basic information
Product Name:Bis(triphenylphosphinepalladium) acetate
Synonyms:Diacetatobis(triphenylphosphine)palladium(II) Store refrigerated;Bis(acetato)bis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) diacetate;Palladium, bis(acetato-O)bis(triphenylphosphine)-;Diacetatobis(triphenylphosphine)palladium(II), Pd 14.2%;Diacetatobis(Triphenylphosphosphate) PalladiuM;Bis(triphenylphosphine)palladium(II) acetate,99%;Diacetatobis(triphenylphosphine)palladiuM(II),98% (PPh3)2Pd(OAc)2;Bis(triphenylphosphinepalladiu
CAS:14588-08-0
MF:C40H36O4P2Pd
MW:749.08
EINECS:238-628-4
Product Categories:metal-phosphine complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Metal Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;chemical reaction,pharm,electronic,materials;Halogenated Heterocycles ,Pyrimidines;Pd
Mol File:14588-08-0.mol
Bis(triphenylphosphinepalladium) acetate Structure
Bis(triphenylphosphinepalladium) acetate Chemical Properties
Melting point 136 °C (dec.)(lit.)
storage temp. Inert atmosphere,Store in freezer, under -20°C
form Powder
color Yellow
Stability:store cold
InChIInChI=1S/2C18H15P.2C2H4O2.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2(3)4;/h2*1-15H;2*1H3,(H,3,4);/q;;;;+2/p-2
InChIKeyOZELLBKLLRMCRL-UHFFFAOYSA-M
SMILESP(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1.O(C(=O)C)[Pd]OC(=O)C
Safety Information
Hazard Codes Xn
Safety Statements 22-24/25
WGK Germany 3
1-3-10
HS Code 28439000
MSDS Information
ProviderLanguage
Diacetatobis(triphenylphosphine)palladium (II) English
SigmaAldrich English
ACROS English
Bis(triphenylphosphinepalladium) acetate Usage And Synthesis
Chemical Propertiesyellow powder
Usessuzuki reaction
UsesBis(triphenylphosphine)palladium(II) diacetate can be used as a catalyst for C-C bond formation via Sonogashira coupling, Negishi coupling, Heck coupling, and Suzuki coupling reaction.
It can also be used as a catalyst to synthesize:
  • Pyrido[1,2-a]benzimidazole derivatives by electro-oxidative intramolecular C-H/N-H annulation reaction.
  • α, β-Unsaturated carboxylic acids by hydroxycarbonylation of vinyl triflates.
  • Secondary imides by C-H functionalization of aldehydes with different N-substituted N-heteroarene-2-carboxamides.

Bis(triphenylphosphinepalladium) acetate Preparation Products And Raw materials
dichlorobis(di-tert-butylphenylphosphine)palladium(II) Tocopheryl acetate Palladium (II) Acetate Sodium acetate Palladium hydroxide TRIPHENYLPHOSPHINE Palladium Bis(triphenylphosphinepalladium) acetate (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Butyl acetate ACETATE Ethyl acetate Glatiramer acetate Vinyl acetate Potassium Acetate Triphenylphosphine Methyl acetate Bis(triphenylphosphine)palladium(II) chloride

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