ChemicalBook Product Catalog Chemical Reagents Organic reagents Cyanide / nitrile Methylenaminoacetonitrile

Methylenaminoacetonitrile

Methylenaminoacetonitrile Basic information
Product Name:Methylenaminoacetonitrile
Synonyms:(methyleneamino)-acetonitril;Glycinonitrile, n-methylene-;-Hydroformaminecyanide;maan;methyleniminoacetonitrile;n-methylene-glycinonitril;usafdo-5;N-Methylenaminoacetonitrile
CAS:109-82-0
MF:C3H4N2
MW:68.08
EINECS:203-709-5
Product Categories:
Mol File:109-82-0.mol
Methylenaminoacetonitrile Structure
Methylenaminoacetonitrile Chemical Properties
Melting point 127-130 °C
Boiling point 106.45°C (rough estimate)
density 0.8765 (rough estimate)
refractive index 1.4089 (estimate)
solubility slightly sol. in Benzene
form powder to crystal
pka3.30±0.50(Predicted)
color White to Almost white
Merck 14,6057
BRN 1848155
Exposure limitsNIOSH: IDLH 25 mg/m3
CAS DataBase Reference109-82-0(CAS DataBase Reference)
NIST Chemistry ReferenceMethyleneaminoacetonitrile(109-82-0)
EPA Substance Registry SystemAcetonitrile, (methyleneamino)- (109-82-0)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 36/37/39-26-22
RTECS MC1925000
TSCA Yes
HS Code 2926.90.5050
MSDS Information
ProviderLanguage
N-Methylenaminoacetonitrile English
ACROS English
ALFA English
Methylenaminoacetonitrile Usage And Synthesis
Chemical PropertiesWHITE CRYSTALS
Purification MethodsCrystallise MAAN from EtOH or acetone. It crystallises nicely from H2O but with considerable loss of material. It is an inhibitor of bone growth. [Adams & Langley Org Synth Coll Vol I 355 1941.]
Methylenaminoacetonitrile Preparation Products And Raw materials
Preparation ProductsGlycine-->AMINOACETONITRILE
2-AMINO-1-(1-AZA-2-(2-THIENYL)VINYL)ETHENE-1,2-DICARBONITRILE 2-AMINO-1-(1-AZA-2-(2,4-DICHLOROPHENYL)VINYL)ETHENE-1,2-DICARBONITRILE 2-AMINO-1-(1-AZA-2-(2-(4-METHYLPHENYLTHIO)-5-NITROPHENYL)VINYL)ETHENE-1,2-DICARBONITRILE Emamectin Aminoacetonitrile hydrochloride AMINOACETONITRILE 2-AMINO-1-(1-AZA-2-(2-(4-CHLOROPHENYLTHIO)-5-NITROPHENYL)VINYL)ETHENE-1,2-DICARBONITRILE AMINOACETONITRILE HYDROGEN SULFATE 2-AMINO-1-(1-AZA-2-(3,4,5-TRIMETHOXYPHENYL)VINYL)ETHENE-1,2-DICARBONITRILE 2-AMINO-1-(1-AZA-2-(5-NITRO-2-(2-PYRIDYLTHIO)PHENYL)VINYL)ETHENE-1,2-DICARBONITRILE (3-Methoxyphenyl)acetonitrile Methylenaminoacetonitrile 2-AMINO-1-(1-AZA-2-(3-CHLOROPHENYL)VINYL)ETHENE-1,2-DICARBONITRILE N-(Diphenylmethylene)aminoacetonitrile 1-AMINO-2-[1-AZA-2-(2-HYDROXY-3-METHOXYPHENYL)VINYL]ETHENE-1,2-DICARBONITRILE 2-AMINO-1-(1-AZA-2-(3,4-DIHYDROXYPHENYL)VINYL)ETHENE-1,2-DICARBONITRILE P-AMINOBENZAMIDE GLUTAMIC ACID Iminodiacetonitrile
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