2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Basic information
Reactions
Product Name:2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Synonyms:2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos);BrettPhos 96%;2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos;2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl;BRETTPHOS;Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
CAS:1070663-78-3
MF:C35H53O2P
MW:536.77
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File:1070663-78-3.mol
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Structure
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Chemical Properties
Melting point 191-193℃
Boiling point 607.7±55.0 °C(Predicted)
storage temp. Refrigerator, under inert atmosphere
solubility Chloroform (Slightly), Methanol (Slightly, Sonicated)
form crystal
color white
InChIKeyWDVGNXKCFBOKDF-UHFFFAOYSA-N
Safety Information
Risk Statements 36/37/38
Safety Statements 26-37-60
WGK Germany nwg
TSCA No
HS Code 2931499090
MSDS Information
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Usage And Synthesis
Reactions
  1. Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
  2. Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
  3. Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
  4. Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
  5. Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
  6. Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
  7. Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
  8. Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.
Reactions of 1070663-78-3_1
Reactions of 1070663-78-3_2
UsesLigand for the Suziki-Miyaura coupling of tosylates and mesylates.
UsesBuchwald Phosphine Ligands for chemical Synthesis
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Preparation Products And Raw materials
Preparation ProductsMethanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
2-(Diphenylphosphino)-biphenyl 2-Dicyclohexylphosphino-2',6'-bis(diMethylaMino)-1,1'-biphenyl, Min. 98% Cphos Potassium tert-butoxide 1,1'-Bis(diphenylphosphino)ferrocene X-PHOS 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL 2-(Dicyclohexylphosphino)-2'-methoxybiphenyl 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2-(Diphenylphosphino)benzoic acid Palladium chloride 2'-(dicyclohexylphosphino)-6-methoxy-N,N-dimethylbiphenyl-2-amine Sodium tert-butoxide 2-(Dicyclohexylphosphino)biphenyl 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl Triphenylphosphine 2-(Dicyclohexylphosphino)-2'-methylbiphenyl 2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Tri-tert-butylphosphine

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