1,7-DIAZA-12-CROWN-4

1,7-DIAZA-12-CROWN-4 Basic information
Product Name:1,7-DIAZA-12-CROWN-4
Synonyms:1,7-DIAZA-12-CROWN-4;4,10-DIAZA-12-CROWN 4-ETHER;4,10-dioxa-1,7-diazacyclododecane;1,7-Diaza-12-crown-4 >=97.0%;1,7-Diaza-12-crown-4,98%;4,10-Diaza-12-crown4-Ether>;diaza[12]crown-4;1,7-DIOXA-4,10-DIAZACYCLODODECANE
CAS:294-92-8
MF:C8H18N2O2
MW:174.24
EINECS:206-034-4
Product Categories:Azacrown Ethers;Crown Ethers;Functional Materials;Macrocycles for Host-Guest Chemistry
Mol File:294-92-8.mol
1,7-DIAZA-12-CROWN-4 Structure
1,7-DIAZA-12-CROWN-4 Chemical Properties
Melting point 86 °C
Boiling point 305.23°C (rough estimate)
density 1.0752 (rough estimate)
refractive index 1.4540 (estimate)
storage temp. Inert atmosphere,2-8°C
pka9.09±0.20(Predicted)
form powder to crystal
color White to Light yellow
BRN 606115
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
HS Code 2934.99.9001
MSDS Information
1,7-DIAZA-12-CROWN-4 Usage And Synthesis
Chemical Propertieswhite to slightly yellow needle like
Uses1,7-Diaza-12-crown-4 can be used to prepare:
  • A ligand named N,N′-bis[(6-carboxy-2-pyridyl)methyl]-1,7-diaza-12-crown-4, which is used to synthesize lanthanide metal complexes applicable as MRI contrast agents.
  • A novel chiral receptor that can be used in the separation of enantiomers using capillary electrophoresis.
  • A fluorescent anthracene based diazacrown ether, which can be used as a photoinduced electron transfer (PET) fluorescent sensor for guest cations.

18-Crown-6 12-Crown-4 15-Crown-5 1,4,7-TRIOXA-10-AZACYCLODODECANE BENZO-12-CROWN-4 N,N'-BIS(METHOXYMETHYL)DIAZA-12-CROWN-4 KRYPTOFIX(R) 211 2-(HYDROXYMETHYL)-12-CROWN 4-ETHER 1,7-DIAZA-12-CROWN-4 N,N'-BIS(METHOXYMETHYL)DIAZA-12-CROWN-4, 90,N,N'-BIS (METHOXYMETHYL) DIAZA-12-CROWN-4 90% KRYPTOFIX 111

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