1-VINYLNAPHTHALENE

1-VINYLNAPHTHALENE Basic information
Product Name:1-VINYLNAPHTHALENE
Synonyms:1-(1-Naphtyl)ethene;1-Vinylnaphthalene, 95%, stab. with 4-tert-Butylcatachol;ALPHA-VINYLNAPHTHALENE;1-VINYLNAPHTHALENE;1-ETHENYLNAPHTHALENE;1-Vinylnaphthalene (stabilized with TBC);(Naphthalen-1-yl)ethene;1-Vinylnaphthalene 
CAS:826-74-4
MF:C12H10
MW:154.21
EINECS:212-560-5
Product Categories:Naphthalene series;Aromatics Compounds;Aromatics;Mutagenesis Research Chemicals;Monomers;NLO MonomersPolymer Science;Non-Linear Optical (NLO) Materials;Photonic and Optical Materials;Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
Mol File:826-74-4.mol
1-VINYLNAPHTHALENE Structure
1-VINYLNAPHTHALENE Chemical Properties
Melting point 322 °C
Boiling point 135-138 °C (lit.)
density 1.04 g/mL at 25 °C (lit.)
refractive index n20/D 1.653(lit.)
Fp 101 °C
storage temp. -20°C
solubility Soluble in ethyl acetate, hexane and methanol.
form Oil
color Colourless to Orange
Sensitive Moisture Sensitive
Stability:Stable. Incompatible with strong oxidizing agents. Combustible.
CAS DataBase Reference826-74-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,N,Xn
Risk Statements 36/37/38-51/53-22
Safety Statements 26-36-61
RIDADR UN 3082 9 / PGIII
WGK Germany 2
HS Code 29029090
MSDS Information
ProviderLanguage
SigmaAldrich English
1-VINYLNAPHTHALENE Usage And Synthesis
Chemical PropertiesColourless to Pale Green Liquid
Uses1-Vinylnaphthalene is used as a precursor of polynuclear aromatic hydrocarbons in tobacco smoke. It is also used as pharmaceutical intermediate.
Uses1-Vinylnaphthalene may be used in the synthesis of 1-naphthyl-1,2-ethanediol, which can further be utilized as a metal hydrogenated catalyst. It may also be used as a substrate material to produce azidocyanation based products.
DefinitionChEBI: 1-vinylnaphthalene is a vinylnaphthalene.
Synthesis Reference(s)Tetrahedron, 52, p. 915, 1996 DOI: 10.1016/0040-4020(95)00950-7
Purification MethodsCommercial material can contain up to 2% of poly-1-vinylnaphthalene. Fractionally distil it under reduced pressure using a spinning-band column, dry it with CaH2 and again distil it under vacuum. Store it in sealed ampoules in a freezer. It has max (cyclohexane) at 210 and 320nm. The picrate has m 105-106o. [Beilstein 5 H 585, 5 III 1773, 5 IV 1833.] It is an irritant.
1-VINYLNAPHTHALENE Preparation Products And Raw materials
Preparation Products1,4-CHRYSENEQUINONE
NAPHTHOCHROME GREEN 1-STYRYLNAPHTHALENE Poly(2-vinylnaphthalene)(MW~175000) 1,2,3,4,4a,7,8,8a-Octahydro-5-hydroxymethyl-α,1,2,4a-tetramethyl-α-vinylnaphthalene-1-(1-propanol) PERINAPHTHENONE 1-(4-CHLOROPHENYL)-3-(1-NAPHTHYL)PROP-2-EN-1-ONE VICTORIA BLUE 4R 3-HYDROXY-1H-PHENALEN-1-ONE 1-(4-METHYLPHENYL)-3-(1-NAPHTHYL)PROP-2-EN-1-ONE CYANOL GREEN Basic Blue 7 1-vinylpyrene 2-(1-VINYLNAPHTHALENE)INDOLE Poly(1-vinylnaphthalene)(~100,000) poly(sodium styrenesulfonate-co-2-vinylnaphthalene) Poly(2-vinylnaphthalene)(MW~50000) 3-(1-NAPHTHYL)-1-(4-NITROPHENYL)PROP-2-EN-1-ONE 9-(2-nitrovinyl)anthracene

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