2,6-Dichloro-1-fluoropyridinium triflate

2,6-Dichloro-1-fluoropyridinium triflate Basic information
Product Name:2,6-Dichloro-1-fluoropyridinium triflate
Synonyms:N-Fluoro-2,6-dichloropyridinium triflate 97%;N-Fluoro-2,6-dichloropyridiniumtriflate97%;N-FLUORO-2,6-DICHLOROPYRIDINIUM TRIFLATE;1-FLUORO-2,6-DICHLOROPYRIDINIUM TRIFLATE;2,6-DICHLORO-1-FLUOROPYRIDINIUM TRIFLATE;2,6-DICHLORO-1-FLUOROPYRIDINIUM TRIFLUOROMETHANESULFONATE;1-FLUORO-2,6-DICHLOROPYRIDINIUM TRIFLATE 94+%;2,6-Dichloro-1-fluoropyridinium Trifluoromethanesulfonate [Fluorinating Reagent]
CAS:130433-68-0
MF:C6H3Cl2F4NO3S
MW:316.06
EINECS:
Product Categories:Electrophilic Fluorinating Reagents;Fluorinating Reagents;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Fluorination;Chemical Synthesis;Fluorination Reagents;Halogenation;Pyridinium Compounds;Synthetic Organic Chemistry;Synthetic Reagents
Mol File:130433-68-0.mol
2,6-Dichloro-1-fluoropyridinium triflate Structure
2,6-Dichloro-1-fluoropyridinium triflate Chemical Properties
Melting point 176-182 °C
storage temp. 2-8°C
form Powder
color white to light-yellow
Sensitive air sensitive, moisture sensitive, store cold
CAS DataBase Reference130433-68-0(CAS DataBase Reference)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-35
Safety Statements 45-36/37/39-26
RIDADR UN 3261 8 / PGII
WGK Germany 3
TSCA No
HazardClass IRRITANT
HS Code 29333999
MSDS Information
ProviderLanguage
ACROS English
2,6-Dichloro-1-fluoropyridinium triflate Usage And Synthesis
Chemical Propertiesyellow powder
Uses2,6-Dichloro-1-fluoropyridinium triflate can be used in the fluorination of various organic compounds.
UsesN-fluoropyridinium triflate salts offer a tunable fluorinating system; electronic nature of the substituents on the ring dictates the potency and selectivity of the reagent. Efficient fluorination of various aromatics, carbanions, vinyl esters, alkyls, and enamines.
Uses
  • Used in the fluorination of various organic compounds
  • Fluoropyridinium triflates are versatile reagents for transformation of thioglycosides into ο-glycoside, glycosyl azide and sulfoxide
  • Electrolytic partial fluorination and diastereoselective anodic fluorination
  • Regioselective, electrochemical fluorination
  • Fluorination of alkenes with N-F type of reagents
2,6-Dichloro-1-fluoropyridinium triflate Preparation Products And Raw materials
Raw materialsTrifluoromethanesulfonic acid-->2,6-Dichloropyridine
AMMONIUM TRIFLUOROMETHANESULFONATE PYRIDINIUM TRIFLUOROMETHANESULFONATE 2,6-Dichloro-1-fluoropyridinium triflate 1-FLUOROPYRIDINIUM TRIFLATE N-FLUORO-3,5-DICHLOROPYRIDINIUM TRIFLATE,1-Fluoro-3,5-dichloropyridinium triflate

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