TRIMETHYL(PHENYLSELENO)SILANE

TRIMETHYL(PHENYLSELENO)SILANE Basic information
Product Name:TRIMETHYL(PHENYLSELENO)SILANE
Synonyms:(PHENYLSELENO)TRIMETHYLSILANE;PHENYLTRIMETHYLSILYLSELENIDE;(TRIMETHYLSILYLSELENO)BENZENE;TRIMETHYLSILYL PHENYL SELENIDE;TRIMETHYL(PHENYLSELENO)SILANE;Trimethyl(phenylseleno)silane,tech.ca90%;Trimethyl(phenylseleno)silanetech.ca90%;Trimethyl(phenylseleno)silane, tech., ca. 90%
CAS:33861-17-5
MF:C9H14SeSi
MW:229.25
EINECS:
Product Categories:
Mol File:33861-17-5.mol
TRIMETHYL(PHENYLSELENO)SILANE Structure
TRIMETHYL(PHENYLSELENO)SILANE Chemical Properties
Melting point -14--9°
Boiling point 51-53 °C (0.3 mmHg)
density d2020 1.1960
refractive index 1.5515-1.5555
solubility sol benzene, Et2O, THF, MeCN.
Specific Gravity1.196
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Safety Information
Hazard Codes N-T
Risk Statements 50/53-33-23/25
Safety Statements 61-60-45-28A-20/21
TSCA No
MSDS Information
ProviderLanguage
ACROS English
ALFA English
TRIMETHYL(PHENYLSELENO)SILANE Usage And Synthesis
Chemical Propertiesclear yellow liquid
Physical propertiesbp 92–93 °C/5 mmHg.
UsesPhenyl Trimethylsilyl Selenide is widely used in synthesis of benzeneselenol; introduction of the phenylseleno function into a variety of oxygen-containing compounds.
UsesSelenating reagent.
PreparationPhenyl Trimethylsilyl Selenide is conveniently prepared by the reduction of diphenyl diselenide with sodium in THF, followed by silylation of thus formed PhSeNa with chlorotrimethylsilane. In a small scale reaction, silylation of PhSeLi, which can be prepared in situ from metallic selenium and phenyllithium in THF, is alternatively utilized.
TRIMETHYL(PHENYLSELENO)SILANE Preparation Products And Raw materials
Preparation ProductsChlorotrimethylsilane
PHENYLSELENOL TRIMETHYL(PHENYLSELENO)SILANE TRIMETHYL(PHENYLSELENO)SILANE,TRIMETHYL(PHENYLSELENO)SILANE TECH., CA. 90% (GC)

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