Naphthionic acid

Naphthionic acid Basic information
Product Name:Naphthionic acid
Synonyms:4-AMINO-1-NAPHTHALENESULPHONICACID;1-Naphthylamine-4-sulfonic acid, Naphthionic acid;4-Amino-1-naphthalenesulfonic acid,98%;4-Aminonaphthalene-1-sulfonic acid for synthesis;alpha-naphthylamine-p-sulfonicacid;Kyselina 1-naftylamin-4-sulfonova;Kyselina nafthionova;kyselina1-naftylamin-4-sulfonova
CAS:84-86-6
MF:C10H9NO3S
MW:223.25
EINECS:201-567-9
Product Categories:Intermediates of Dyes and Pigments;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfonic/Sulfinic Acids;Sulfur Compounds
Mol File:84-86-6.mol
Naphthionic acid Structure
Naphthionic acid Chemical Properties
Melting point ≥300 °C(lit.)
Boiling point 220°C (rough estimate)
density 1.67
refractive index 1.5250 (estimate)
storage temp. Store below +30°C.
solubility Sparingly soluble in dichloromethane. Soluble in aqueous base.
pkapK1: 2.81 (25°C)
form powder to crystal
color White to Light yellow to Light red
Water Solubility 309.9mg/L(20 ºC)
Merck 14,6403
BRN 1971299
CAS DataBase Reference84-86-6(CAS DataBase Reference)
NIST Chemistry Reference4-Amino-1-naphthalene sulfonic acid(84-86-6)
EPA Substance Registry System4-Amino-1-naphthalenesulfonic acid (84-86-6)
Safety Information
Hazard Codes C
Risk Statements 34-22
Safety Statements 26-36/37/39-45-25
RIDADR UN 2585 8/PG 3
WGK Germany 3
RTECS QK1270000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29214500
MSDS Information
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Naphthionic acid English
SigmaAldrich English
ACROS English
ALFA English
Naphthionic acid Usage And Synthesis
Chemical Propertiesslightly greyish to beige powder and granules
UsesIntermediate for azo dyes, e.g., Congo red.
Uses4-Amino-1-naphthalenesulfonic acid has potent therapeutic applications. Its sodium salt has been used as non-toxic hemostatic. It is also a metabolite of azo dyes.
DefinitionChEBI: Naphthionic acid is an aminonaphthalenesulfonic acid.
General Description4-Amino-1-naphthalenesulfonic acid is a diazo compound. It is also known as Piria′s acid.
Purification MethodsIt crystallises from H2O as needles of the 0.5 hydrate. Salt solutions fluoresce strongly blue. The S-benzylisothiuronium salt has m 195o (from aqueous EtOH). [Beilstein 14 IV 2793.]
Direct Blue 53 CHICAGO SKY BLUE 6B 1-AMINO-8-NAPHTHOL-4-SULFONIC ACID Mordant Black 17 Ascoric Acid ACID RED 88 4-Amino-benzenesulfonic acid monosodium salt Ammonium sulfamate SULFONIC ACID Stearic acid Folic acid 1-Amino-2-naphthol-4-sulfonic acid Eriochrome Black T Naphthionic acid Mordant Black 3 C.I. 14720 Molasses Citric acid

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