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| | PHENYLSELENENYL CHLORIDE Basic information |
| | PHENYLSELENENYL CHLORIDE Chemical Properties |
| Melting point | 59-62 °C (lit.) | | Boiling point | 120 °C/20 mmHg (lit.) | | Fp | 120°C/20mm | | storage temp. | Store below +30°C. | | solubility | Soluble in methanol. | | form | crystal | | color | red | | Sensitive | Moisture Sensitive | | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | | BRN | 1237091 | | Exposure limits | ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 | | Stability: | Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents. | | InChI | InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H | | InChIKey | WJCXADMLESSGRI-UHFFFAOYSA-N | | SMILES | C1([Se]Cl)=CC=CC=C1 | | CAS DataBase Reference | 5707-04-0(CAS DataBase Reference) |
| | PHENYLSELENENYL CHLORIDE Usage And Synthesis |
| Chemical Properties | crystalline solid | | Uses | Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols. | | General Description | Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis. | | Purification Methods | Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC. |
| | PHENYLSELENENYL CHLORIDE Preparation Products And Raw materials |
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