6-tert-Butyl-m-cresol

6-tert-Butyl-m-cresol Basic information
Product Name:6-tert-Butyl-m-cresol
Synonyms:1-tert-butyl-2-hydroxy-4-methyl-benzen;2-(1,1-dimethylethyl)-5-methyl-pheno;2-(1,1-dimethylethyl)-5-methylphenol;2-(1,1-dimethylethyl)-5-methyl-Phenol;2-TERT-BUTYL-5-METHYLPHENOL;5-METHYL-2-TERT-BUTYLPHENOL;2-1,1-dimethylethyl-5-methyl-phenol;2-t-Butyl-5-methylphenol
CAS:88-60-8
MF:C11H16O
MW:164.24
EINECS:201-842-3
Product Categories:Antioxidant;Organics;Industrial/Fine Chemicals;Miscellaneous
Mol File:88-60-8.mol
6-tert-Butyl-m-cresol Structure
6-tert-Butyl-m-cresol Chemical Properties
Melting point 20 °C
Boiling point 117-118 °C12 mm Hg(lit.)
density 0.964 g/mL at 25 °C(lit.)
vapor pressure 3Pa at 23℃
refractive index n20/D 1.519(lit.)
Fp 222 °F
storage temp. Inert atmosphere,Room Temperature
Water Solubility Insoluble in water
pka11.45±0.10(Predicted)
form Notspecified
color Colorless to Red to Green
Specific Gravity0.9590.964
Odorat 0.10 % in dipropylene glycol. russian leather
Odor Typeanimal
LogP3.97
CAS DataBase Reference88-60-8(CAS DataBase Reference)
NIST Chemistry ReferencePhenol, 2-(1,1-dimethylethyl)-5-methyl-(88-60-8)
EPA Substance Registry System6-tert-Butyl-m-cresol (88-60-8)
Safety Information
Hazard Codes Xn,C
Risk Statements 22-36/37/38-34
Safety Statements 26-36/37/39-45
RIDADR UN 3145 8/PG 3
WGK Germany 2
RTECS SK1578180
HazardClass 8
PackingGroup III
HS Code 29071990
Hazardous Substances Data88-60-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
6-tert-Butyl-m-cresol English
SigmaAldrich English
ACROS English
6-tert-Butyl-m-cresol Usage And Synthesis
Chemical Propertiesclear colorless viscous liquid
Synthesis Reference(s)Tetrahedron Letters, 31, p. 6977, 1990 DOI: 10.1016/S0040-4039(00)97220-4
General DescriptionA clear colorless liquid. Flash point 116°F. Melting point 74°F. Less dense than water and insoluble in water. Used as a disinfectant, to make rubber, as a lubricating oil additive, and for many other uses.
Air & Water ReactionsFlammable. Insoluble in water.
Reactivity ProfilePhenols, such as 6-tert-Butyl-m-cresol, do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
3-tert-Butylphenol 4-tert-Butylcatechol Cyhalofop-butyl 4-tert-Butylphenol 3-Ethylphenol tert-Butyl methyl ether tert-Butyldimethylsilyl chloride tert-Butyl hydroperoxide Buprofezin Methyl 4-tert-butylbenzoate tert-Butanol Diethylene glycol monobutyl ether Cresol Butyl acrylate Butyl acetate m-Cresol Di-tert-butyl peroxide 2-Butoxyethanol

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