Fennel Oil

Fennel Oil Basic information
Product Name:Fennel Oil
Synonyms:bitterfenchel;Bitterfenneloil;Foeniculum Vulcare Mill.;Foeniculum vulgare Mill.;fencheloel;fenouilamer(french);fenouildoux(french);finocchio
CAS:8006-84-6
MF:
MW:0
EINECS:
Product Categories:Natural Plant Extract;Flavors & Fragrances;Natrual plant extract
Mol File:Mol File
Fennel Oil Structure
Fennel Oil Chemical Properties
Melting point 5 °C(lit.)
alpha aD25 +12 to +24°
Boiling point 227 °C(lit.)
density 0.963 g/mL at 25 °C(lit.)
FEMA 2483 | FENNEL OIL, SWEET (FOENICULUM VULGARE MILL. VAR. DULCE DC.)
refractive index n20/D 1.538(lit.)
Fp 140 °F
Odorat 100.00 %. licorice
Odor Typeminty
optical activity[α]22/D +18°, neat
EPA Substance Registry SystemOils, fennel (8006-84-6)
Safety Information
Hazard Codes Xi
Risk Statements 38
RIDADR UN 1993 3/PG 3
WGK Germany 2
RTECS LJ2550000
HazardClass 3
PackingGroup III
Hazardous Substances Data8006-84-6(Hazardous Substances Data)
toxicityThe acute oral LD50 in rats was reported as 3.8 g/kg (3.43-4.17 g/kg) (Moreno, 1973). The acute dermal LD50 in rabbits exceeded 5 g/kg (Moreno, 1973).
MSDS Information
ProviderLanguage
SigmaAldrich English
Fennel Oil Usage And Synthesis
Chemical PropertiesFennel oil is obtained by steam distillation of the aerial parts of Foeniculum vulgare Mill. ssp. vulgare var. vulgare (bitter fennel). It is a colorless to pale yellow liquid with a camphoraceous, sweet–spicy odor and a slightly bittersweet camphoraceous taste, d2020 0.944–0.973; n20D 1.514–1.538; α20D +11 ° to +29 °. The main constituents are monoterpene hydrocarbons such as ??-phellandrene (0–8.5%) and limonene (1–6%), fenchone (10–25%), estragole (1–6%), and (E)-anethole (50–78%). With increasing maturity of the fruits, the content of monoterpenes decreases. The ripe fruits yield an oil with 50–70% anethole and 5–25% fenchone. In contrast, the oil of the ripe fruits of sweet fennel (F. vulgare Mill. ssp. vulgare var. dulce) contains less than 5% fenchone and more than 75% anethole.
Fennel oil is produced mainly in Hungary, Tasmania, North Africa, and India in a quantity of few 10 t/yr. In total. It is used in flavoring oral care products and alcoholic beverages (anise liqueurs).
Chemical PropertiesThe oil is obtained by steam distillation of the seeds Fennel sweet oil has a characteristic anise odor.
Chemical PropertiesThe oil is obtained by steam distillation of the dried, comminuted seeds in varying yields, usually from 2 5 to 6 5%, depending on the plant origin It has an aromatic, spicy odor and an initially slightly bitter, camphoraceous, then sweet, favor.
Physical propertiesIt is a colorless to pale-yellow liquid.
Physical propertiesIt is a yellowish-green liquid.
OccurrenceFound in the plant Foeniculum vulgare Thellung (Fam. Umbelliferae) (Guenther, 1950).
UsesFlavoring agent in foods and pharmaceuticals. Fennel Oil can be used in eye washes and in facial steams to soothe and clean skin.
PreparationBy steam distillation of the seeds of Foeniculum vulgare (Fenarolfs Handbook of Flavor Ingredients, 1971).
DefinitionExtractives and their physically modified derivatives. Foeniculum vulgare, Umbelliferae.
Essential oil compositionThe main constituents of the oil include anethole, d-phellandrene and d-limonene.
Essential oil compositionThe oil contains up to 90% trans-anethole and up to 20% fenchone and small amounts of limonene, α-pinene, camphor and additional volatile compounds.
Safety ProfileModerately toxic by ingestion. Mutation data reported. A severe skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Fennel Oil Preparation Products And Raw materials
Raw materialsAnise oil
Preparation Productsp-Anisaldehyde-->cis-Anethol-->trans-Anethole
Aluminum acetylacetonate METHYL ISOCYANOACETATE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) N-BUTYLISOCYANIDE PHENYLSELENOL Tris(2,4-pentanedionato)chroMiuM(III) DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) SALCOMINE 2,4-PENTANEDIONE, SILVER DERIVATIVE 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE Tosylmethyl isocyanide Cupric acetylacetonate Ethyl isocyanoacetate TERT-BUTYL ISOCYANIDE Ferric acetylacetonate COBALT ETHYLENE DIAMINE CHLORIDE Benzyl isocyanide TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III)

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