AMMONIUM FERROCYANIDE

AMMONIUM FERROCYANIDE Basic information
Product Name:AMMONIUM FERROCYANIDE
Synonyms:AMMONIUM HEXACYANOFERRATE II;AMMONIUM FERROCYANIDE;IRON (II) AMMONIUM FERROCYANIDE;FERROUS AMMONIUM CYANIDE;ammoniumferrocyanide[(nh4)4(fe(cn)6)];hexacyano-ferrate(4-tetraammonium;hexakis(cyano-C)-,tetraammonium,(OC-6-11)-Ferrate(4-);tetraammonium,(oc-6-11)-ferrate(4-hexakis(cyano-c)-
CAS:14481-29-9
MF:C6H16FeN10
MW:284.1
EINECS:238-476-9
Product Categories:metal cyano complex
Mol File:14481-29-9.mol
AMMONIUM FERROCYANIDE Structure
AMMONIUM FERROCYANIDE Chemical Properties
Melting point >300°C
form Powder
color yellow to green
Water Solubility trihydrate soluble H2O [MER06]
Sensitive Light Sensitive & Hygroscopic
Merck 14,520
CAS DataBase Reference14481-29-9(CAS DataBase Reference)
EPA Substance Registry SystemFerrate(4-), hexakis(cyano-.kappa.C)-, tetraammonium, (OC-6-11)- (14481-29-9)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 26-36/37
WGK Germany 3
8
TSCA Yes
HS Code 28372000
Hazardous Substances Data14481-29-9(Hazardous Substances Data)
MSDS Information
AMMONIUM FERROCYANIDE Usage And Synthesis
Chemical Propertiesgreen fine crystalline powder
UsesAmmonium Hexacyanoferrate(II) is used for the detection of calcium by spot test. A hazardous chemical compound and a useful reagent for the preparation of heterometallic complexes.
Safety ProfileA poison. Reacts explosively withmetal nitrates when heated, e.g., cobalt(II) nitrate at 220°Cand copper(II) nitrate at 220°C. When heated todecomposition it emits toxic fumes of CN?? and NH3. Seealso CYANIDE.
Purification MethodsThe pale yellow trihydrate powder can be washed with 10% aqueous NH3, filtered, then washed several times with EtOH and Et2O, and dried at room temperature. It decomposes in a vacuum above 100o and should be stored away from light and under N2. In light and air it decomposes by losing NH3. [Lux in Handbook of Preparative Inorganic Chem (Ed. Brauer) Academic Press Vol II p 1509 1965.]
AMMONIUM FERROCYANIDE Preparation Products And Raw materials
Preparation ProductsPrussian Blue
DIAMMONIUM COBALT(II) SULFATE HEXAHYDRATE Aluminium ammonium sulfate dodecahydrate AMMONIUM MAGNESIUM SULFATE HEXAHYDRATE Ammonia monohydrate CYANOGEN CALCIUM AMMONIUM FERROCYANIDE AMMONIUM FERROCYANIDE AMMONIUM FERROCYANIDE HYDRATE

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