ChemicalBook Product Catalog Organic Chemistry Phosphines TERT-BUTYLDIPHENYLPHOSPHINE

TERT-BUTYLDIPHENYLPHOSPHINE

TERT-BUTYLDIPHENYLPHOSPHINE Basic information
Product Name:TERT-BUTYLDIPHENYLPHOSPHINE
Synonyms:NSC 244302;tert-Butyldiphenylphosphine 97%;(1,1-Dimethylethyl)diphenylphosphine;Diphenyl(tert-butyl)phosphine;TERT-BUTYLDIPHENYLPHOSPHINE;Phosphine,(1,1-dimethylethyl)diphenyl-;tert-butyl(diphenyl)phosphane;TIANFU CHEM TERT-BUTYLDIPHENYLPHOSPHINE
CAS:6002-34-2
MF:C16H19P
MW:242.3
EINECS:227-848-6
Product Categories:Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds
Mol File:6002-34-2.mol
TERT-BUTYLDIPHENYLPHOSPHINE Structure
TERT-BUTYLDIPHENYLPHOSPHINE Chemical Properties
Melting point 52-55 °C(lit.)
Boiling point 144-146 °C2 mm Hg(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
form crystal
color white
InChIKeyQZUPHAGRBBOLTB-UHFFFAOYSA-N
Safety Information
Risk Statements 22-36/37/38
Safety Statements 26-37
WGK Germany 3
TSCA No
MSDS Information
ProviderLanguage
SigmaAldrich English
TERT-BUTYLDIPHENYLPHOSPHINE Usage And Synthesis
UsesNew family of Ph2(t-Bu)P phosphines for efficient Silyl-Heck transformations.
UsesCatalyst for:
  • Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitriles
  • Palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
  • Palladium to form a catalyst for methoxycarbonylation reactions
  • Ru-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydes
  • Stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

  • Phosphine ligand in nickel-catalyzed carbocyanation of alkynes
  • Monodentate P-Donor Ligands (LKB-P)
DefinitionChEBI: NSC 244302 is a member of benzenes.
TERT-BUTYLDIPHENYLPHOSPHINE Preparation Products And Raw materials
DIPHENYL(P-TOLYL)PHOSPHINE DI-T-BUTYLCYCLOHEXYLPHOSPHINE tert-Butyl methyl ether Tert-butyldicyclohexylphosphine tetrafluoroborate tert-Butyldimethylsilyl chloride METHYLDIPHENYLPHOSPHINE DIPHENYL-N-PROPYLPHOSPHINE ETHYLDIPHENYLPHOSPHINE DI-TERT-BUTYLPHENYLPHOSPHINE T-BUTYLDICYCLOHEXYLPHOSPHINE Cyclohexyldiphenylphosphine tert-Butylchlorodiphenylsilane Dicyclohexyl(2-Methylphenyl)phosphine TRIPHENYLMETHYL TRIPHENYLPHOSPHONIUM CHLORIDE T-BUTYLPHOSPHINE ISOPROPYLDIPHENYLPHOSPHINE TERT-BUTYLDIPHENYLPHOSPHINE 1-CARBETHOXYCYCLOPROPYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE
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