3-Chlorobenzotrifluoride

3-Chlorobenzotrifluoride Basic information
Product Name:3-Chlorobenzotrifluoride
Synonyms:1-(trifluoromethyl)-3-chlorobenzene;m-Chloro-(a,a,a-)benzotrifluoride;m-Chloro-alpha,alpha,alpha-trifluorotoluene;m-chlorobenzotriflouride;meta(Trifluoromethyl)chlorobenzene;m-Trifluoromethylphenyl chloride;m-Trifluoromethylphenylchloride;Toluene, m-chloro-alpha,alpha,alpha-trifluoro-
CAS:98-15-7
MF:C7H4ClF3
MW:180.55
EINECS:202-642-9
Product Categories:Aryl;Building Blocks;C7;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Trifluoromethylbenzene serise;Aromatic Hydrocarbons (substituted) & Derivatives;Miscellaneous;Chlorine Compounds;Fluorine Compounds
Mol File:98-15-7.mol
3-Chlorobenzotrifluoride Structure
3-Chlorobenzotrifluoride Chemical Properties
Melting point -56 °C (lit.)
Boiling point 137-138 °C (lit.)
density 1.331 g/mL at 25 °C
refractive index n20/D 1.446(lit.)
Fp 97 °F
form clear liquid
color Colorless to Almost colorless
Specific Gravity1.336
Water Solubility <0.1 g/100 mL at 22 ºC
BRN 510215
Exposure limitsACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
CAS DataBase Reference98-15-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-chloro-3-(trifluoromethyl)-(98-15-7)
EPA Substance Registry System3-Chlorobenzotrifluoride (98-15-7)
Safety Information
Hazard Codes Xi,F
Risk Statements 10-36/37/38
Safety Statements 16-26-36-24/25
RIDADR UN 2234 3/PG 3
WGK Germany 1
RTECS XS9142000
Hazard Note Flammable/Irritant
TSCA T
HazardClass 3
PackingGroup III
HS Code 29039990
MSDS Information
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3-Chlorobenzotrifluoride English
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3-Chlorobenzotrifluoride Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
UsesIntermediate in manufacturing of dyes and pharmaceuticals, dielectrics, insecticides.
Uses3-Chlorobenzotrifluoride is used as an intermediate in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.
General DescriptionA water-white liquid with an odor like moth balls. Flash point between 65-108°F. Insoluble in water and denser than water. Toxic by inhalation. Liquid contact may irritate skin and eyes.
Air & Water ReactionsHighly flammable. On contact with water 3-Chlorobenzotrifluoride can evolve hydrogen fluoride, a highly toxic and corrosive gas. [AAR, 1999]. Insoluble in water and denser than water.
Reactivity ProfileSimple aromatic halogenated organic compounds are very unreactive; halogenated aliphatic compounds are moderately or very reactive. For both subgroups, reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
HazardModerate fire risk.
Health HazardMay cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Purification MethodsPurify it as for o-chlorobenzotrifluoride above. 20 1.4432. [Beilstein 5 III 692, 5 IV 814.]
4-Bromobenzotrifluoride Cyhalothrin Benzotrifluoride 3-Bromobenzotrifluoride 2,4-Dichlorobenzotrifluoride Chloroacetic acid 3-Chlorotoluene Difluorochloromethane 4-Fluorobenzotrifluoride 1,4-Bis(trifluoromethyl)-benzene Trifluoromethyl 3-Fluorobenzotrifluoride Chlorobenzene Epichlorohydrin 3-Aminobenzotrifluoride 2-Methylbenzotrifluoride Diethylstilbestrol 4-Chlorotoluene

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