9,9'-Spirobi[9H-fluorene]

9,9'-Spirobi[9H-fluorene] Basic information
Product Name:9,9'-Spirobi[9H-fluorene]
Synonyms:9,9'-spirobi[9h-fluorene];9,9'-SPIROBIFLUORENE;9,9'-Spirobi[9H-fluorene]9,9'-Spirobi[9H-fluorene];Spirobifluorene;9,9'-Spirobifluorene, Spirobifluorene;9,9'-Spirobi[9H-fluo;JACS-159-66-0;9,9'-Spirobi[9H-fluorene] >
CAS:159-66-0
MF:C25H16
MW:316.39
EINECS:
Product Categories:Halogenated Heterocycles ,Thiophenes ,Thiazolines/Thiazolidines;Electronic Chemicals;Fluorene Derivatives;Fluorene Series
Mol File:159-66-0.mol
9,9'-Spirobi[9H-fluorene] Structure
9,9'-Spirobi[9H-fluorene] Chemical Properties
Melting point 202 °C
Boiling point 474.9±40.0 °C(Predicted)
density 1.28±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form Solid
color White to pale yellow
Water Solubility Soluble in common organic solvents. Slightly soluble in water.
InChIKeySNFCXVRWFNAHQX-UHFFFAOYSA-N
CAS DataBase Reference159-66-0(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29029090
MSDS Information
9,9'-Spirobi[9H-fluorene] Usage And Synthesis
Chemical Propertieswhite powder
UsesA blue light emitting material in organic light emitting diodes (OLEDs). Also used as a blue-emitting material in electroluminescent devices.
Uses9,9′-Spirobifluorene can be used in the synthesis of spirobifluorene based conjugated microporous polymers which can be potentially be used as a gas absorbent. It may be used as a hole transporting material which can be used in the fabrication of perovskite solar cells.
General Description9,9′-Spirobifluorene is a polyfluorene with carbon atoms of the methylene bridge connected to two fluorene molecules. It is mainly used in organic electronics due to its robust structure and two perpendicularly arranged π systems.
9,9'-Spirobi[9H-fluorene] Preparation Products And Raw materials
Preparation Products2,7-Dibromo-9,9'-spiro-bifluorene-->9,9'-spirobi[fluoren]-2-amine-->22,2',7,7'-tetraiodo-9,9'-spirobi[fluorene]-->2,2',7,7'-Tetrabromo-9,9'-spirobifluorene-->2,2'-DIBROMO-9,9'-SPIROBIFLUORENE
9,9-Dimethyl-9H-fluorene 9,9-DIMETHYL-9,10-DIHYDRO-ACRIDINE 9,9-Dihexyl-9H-fluoren-2-boronic acid 9,9-Dimethyl-9H-fluoren-2-yl-boronic acid 9,9-Diphenylfluorene 2-Amino-9,9-dimethylfluorene 2-Amino-9,9-diphenylfluorene 9,9'-Spirobi[9H-fluorene]-4-ylboronicacid 9,9-Dioctyl-2,7-dibromofluorene N,N'-Bis(3-methylphenyl)-N,N'-diphenyl-9,9-spirobifluorene-2,7-diamine Fluorene 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE 2,2',7,7'-Tetrakis(diphenylamino)-9,9'-spirobifluorene 9,9'-SPIROBI[9H-FLUORENE]-3,6-DIAMINE, N3,N3,N6,N6-TETRAPHENYL- 9,9'-Spirobi[9H-fluorene] 2,7-Dibromo-9,9'-spiro-bifluorene 2-Bromo-9,9'-spirobi[9H-fluorene] 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene

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