ChemicalBook Product Catalog Chemical Reagents Organic reagents Thiol / thiol Bis(2-methoxyethyl)aminosulfur trifluoride

Bis(2-methoxyethyl)aminosulfur trifluoride

Bis(2-methoxyethyl)aminosulfur trifluoride Basic information
Product Name:Bis(2-methoxyethyl)aminosulfur trifluoride
Synonyms:BIS(2-METHOXYETHYL)AMINOSULPHUR TRIFLUORIDE;BAST Deoxo-Fluor ,Bis(2-methoxyethyl)aminosulfur trifluoride;2-methoxy-N-(2-methoxyethyl)-N-(trifluoro-λ4-sulfanyl)ethanamine;Bis(6-methoxyethyl)aminosulfur trifluoride;bis(2-methoxyethyl)(trifluoro-λ-sulfanyl)amine;Deoxo-Fluor (Air Prods. Chem.);Bis(2-methoxyethyl)aminosulphur trifluoride (50% solution in THF);DEOXO-FLUOR(R), 50% SOLUTION IN TOLUENE
CAS:202289-38-1
MF:C6H14F3NO2S
MW:221.24
EINECS:478-190-3
Product Categories:Fluorinating Reagents;Nucleophilic Fluorinating Reagents;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Synthetic Organic Chemistry
Mol File:202289-38-1.mol
Bis(2-methoxyethyl)aminosulfur trifluoride Structure
Bis(2-methoxyethyl)aminosulfur trifluoride Chemical Properties
Boiling point >80°C
density 1.2 g/mL at 25 °C(lit.)
refractive index 1.4270 to 1.4310
Fp 205 °F
storage temp. 2-8°C
form liquid
pka-7.46±0.70(Predicted)
Specific Gravity1.2
color clear yellow
Merck 14,2897
InChIKeyAPOYTRAZFJURPB-UHFFFAOYSA-N
CAS DataBase Reference202289-38-1(CAS DataBase Reference)
EPA Substance Registry SystemSulfur, trifluoro[2-methoxy-N-(2-methoxyethyl)ethanaminato-.kappa.N]-, (T-4)- (202289-38-1)
Safety Information
Hazard Codes T,C,F
Risk Statements 14-23/25-29-35-67-65-63-48/20-25-11-40-37-19
Safety Statements 23-26-36/37/39-43-45-8-62-46-25-16
RIDADR UN REST
WGK Germany 3
F 10-21
Hazard Note Toxic/Corrosive
HazardClass KEEP COLD, CORROSIVE
PackingGroup Ⅰ
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Bis(2-methoxyethyl)aminosulfur trifluoride Usage And Synthesis
Chemical PropertiesDark yellow-orange liquid
UsesReactant for:
  • Fluorination reactions
  • Preparation of fluorinated catechols via Umpolung based nucleophilic deoxyfluorination
  • Preparation of imidazole derivatives as CXCR3 antagonists
  • Ring expansion reactions
  • Synthesis of acyl azides from carboxylic acids
  • Aldehydes or ketones from carboxylic acids and Grignard reagents via in situ generation of Weinreb amides
UsesVersatile, thermally stable nucleophilic fluorinating reagent.
Bis(2-methoxyethyl)aminosulfur trifluoride Preparation Products And Raw materials
Raw materialsSilanamine, N,N-bis(2-methoxyethyl)-1,1,1-trimethyl--->BIS(2-METHOXYETHYL)AMINE
Preparation Products1-Bromo-4-(3,3-difluorocyclobutyl)benzene
BIS(2-HYDROXYETHYL)DIMETHYLAMMONIUM CHLORIDE Sulfur tetrafluoride Hexane (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Acid chloride Bis(4-tert-butylphenyl)iodonium hexafluorophosphate Bromobenzene Benzyl bromide Quinolinic acid Indole Fluorine p-(2-Methoxyethyl) phenol DIMETHYLAMINOSULFUR TRIFLUORIDE Methoxydiethylborane Diethylaminosulfur trifluoride Bis(2-methoxyethyl)aminosulfur trifluoride Alexa Fluor 488 Sulfur hexafluoride
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