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| 2,3-DIMETHYL-1,3-BUTADIENE Basic information |
Product Name: | 2,3-DIMETHYL-1,3-BUTADIENE | Synonyms: | 2,3-dimethyl-3-butadiene;2,3-Dimethylenebutane;2,3-Dimethylerythrene,Diiso-propenyl;2,3-DIMETHYL-BUTA-1,3-DIENE;2,3-DIMETHYL-1,3-BUTADIENE;Biisopropenyl;CH2=C(CH3)C(CH3)=CH2;Diisopropenyl | CAS: | 513-81-5 | MF: | C6H10 | MW: | 82.14 | EINECS: | 208-172-0 | Product Categories: | Acyclic;Alkenes;Organic Building Blocks;DID - DINChemical Class;NeatsGasoline, Diesel,&Petroleum;Substance classes;Alpha Sort;D;DAlphabetic;Hydrocarbons;Olefins;Volatiles/ Semivolatiles | Mol File: | 513-81-5.mol | |
| 2,3-DIMETHYL-1,3-BUTADIENE Chemical Properties |
Melting point | ?76 °C (lit.) | Boiling point | 68-69 °C (lit.) | density | 0.726 g/mL at 25 °C (lit.) | vapor pressure | 269 mm Hg ( 37.7 °C) | refractive index | n20/D 1.438(lit.) | Fp | −8 °F | storage temp. | 2-8°C | form | Liquid | color | Clear colorless | Water Solubility | Miscible with chloroform. Immiscible with water. | Merck | 14,3238 | BRN | 605285 | CAS DataBase Reference | 513-81-5(CAS DataBase Reference) | EPA Substance Registry System | 1,3-Butadiene, 2,3-dimethyl- (513-81-5) |
Hazard Codes | F | Risk Statements | 11 | Safety Statements | 16-23 | RIDADR | UN 3295 3/PG 2 | WGK Germany | 3 | F | 9 | TSCA | Yes | HazardClass | 3 | PackingGroup | II | HS Code | 29012900 |
| 2,3-DIMETHYL-1,3-BUTADIENE Usage And Synthesis |
Chemical Properties | Clear colorless liquid | Uses | 2,3-Dimethyl-1,3-butadiene undergoes Diels Alder cycloaddition reaction and it also participates in polymerization reactions. It is also involved in manufacturing of synthetic rubber. | General Description | 2,3-Dimethyl-1,3-butadiene (DMBD) is a conjugated diene. It undergoes Diels Alder cycloaddition reaction with 2-thio-3-chloroacrylamides under thermal, catalytic and microwave conditions. It undergoes thermal [4+2] cycloaddition reaction with 3-acetyl-, 3-carbamoyl and 3-ethoxycarbonylcoumarins under solvent free conditions. DMBD participates in polymerization reactions in the presence of iron dichloride complexes based catalysts. | Purification Methods | Distil it from NaBH4, and purify it by zone melting. [Beilstein 1 IV 1023.] |
| 2,3-DIMETHYL-1,3-BUTADIENE Preparation Products And Raw materials |
Raw materials | Calcium chloride-->Hydroquinone-->Pinacol | Preparation Products | TRIPHENYLMETHYL MERCAPTAN-->1,3-Pentadiene, 2-methyl-, (3Z)--->methoxymethanol-->3,4-Dimethylbenzoic acid-->METHYLPHENYLVINYLSILANE-->4-METHYL-1,3-PENTADIENE-->1,4-DIBROMO-2,3-BIS(BROMOMETHYL)-2-BUTENE-->2,3-Dimethyl-1-butene-->TETRAISOPROPYL ORTHOSILICATE-->DIPHENYLMETHYLETHOXYSILANE-->ALLYLOXYTRIMETHYLSILANE-->2,3,6,7-tetramethylnaphthalene |
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