ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatics 2'-Methylacetoacetanilide

2'-Methylacetoacetanilide

2'-Methylacetoacetanilide Basic information
Product Name:2'-Methylacetoacetanilide
Synonyms:ACETOACET-O-TOLUIDIDE;ACETO ACET O TOLUIDINE;ACETOACET-2-METHYLANILIDE;AAOT;AKOS B029147;Butanamide, N-(2-methylphenyl)-3-oxo-;ACETOACETO-2-TOLUIDINE;2-Acetoacetotoluidide, 99+%
CAS:93-68-5
MF:C11H13NO2
MW:191.23
EINECS:202-267-0
Product Categories:Intermediates of Dyes and Pigments;Aromatic amine products
Mol File:93-68-5.mol
2'-Methylacetoacetanilide Structure
2'-Methylacetoacetanilide Chemical Properties
Melting point 104-106 °C(lit.)
Boiling point 326.97°C (rough estimate)
density 1.06
refractive index 1.5220 (estimate)
Fp 143°C
storage temp. Sealed in dry,Room Temperature
pka11.22±0.46(Predicted)
form powder to crystal
color Crystals
BRN 2099098
LogP0.9 at 23℃
CAS DataBase Reference93-68-5(CAS DataBase Reference)
NIST Chemistry ReferenceButanamide, n-(2-methylphenyl)-3-oxo-(93-68-5)
EPA Substance Registry SystemButanamide, N-(2-methylphenyl)-3-oxo- (93-68-5)
Safety Information
Hazard Codes Xn
Risk Statements 22-20/21/22
Safety Statements 36-36/37-24/25
WGK Germany 1
RTECS AK6550000
TSCA Yes
HS Code 29242990
ToxicityLD50 orl-rat: 1600 mg/kg KODAK* -,N-229,76
MSDS Information
ProviderLanguage
N-(2-Methylphenyl)-3-oxo-butanamide English
ACROS English
SigmaAldrich English
ALFA English
2'-Methylacetoacetanilide Usage And Synthesis
Chemical PropertiesWhite to off-white powder
Uses2'-Methylacetoacetanilide is used as intermediate for the manufacture of organic pigments as well as for the manufacture of agrochemicals.
Safety ProfileModerately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx,.
2'-Methylacetoacetanilide Preparation Products And Raw materials
Raw materialso-Toluidine-->Acetyl ketene-->o-Anisidine-->Acetoxyacetic acid
Preparation ProductsPigment Yellow 14-->4,8-DIMETHYL-2-QUINOLINOL-->2,2-dichloro-N-(2-methylphenyl)acetamide
N-(Acetoacetyl)anthranilic acid N-(5-CHLORO-2-METHYL-PHENYL)-3-OXO-BUTYRAMIDE 2-BENZOYLACETANILIDE 4'-Nitroacetanilide Acetoacetamide N-Methylaniline 3,3',5,5'-Tetramethylbenzidine dihydrochloride p-Acetotoluidide 2',4'-Dimethylacetoacetanilide N-(2,3-DIMETHYLPHENYL)-3-OXOBUTANAMIDE 2'-Methylacetoacetanilide N,N-Dimethylaniline o-Toluidine 2'-NITROACETANILIDE 4'-Aminoacetanilide N,N-Dimethyl-1,4-phenylenediamine 2'-Chloroacetoacetanilide Acetanilide
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