XYLENOL ORANGE

XYLENOL ORANGE Basic information
Product Name:XYLENOL ORANGE
Synonyms:3,3μ-Bis[N,N-bis(carboxymethyl)aminomethyl]-o-cresolsulfonephthalein disodium salt;Xylenol Orange disodium salt;3,3-Bis[3-[[N,N-di(carboxymethyl)amino]methyl]-4-hydroxy-5-methylphenyl]-3H-2,1-benzoxathiole 1,1-dioxide;Cresol Phthalexon S;NSC-324982;o-Cresolphthalexon S;XYLENOL ORANGE, INDI;XYLENOL ORANGE
CAS:1611-35-4
MF:C31H32N2O13S
MW:672.66
EINECS:216-553-8
Product Categories:Sulfonphthalein;Analytical Chemistry;Chelating Reagents;Complexones;Ligands for Pharmaceutical Research;Photometric Reagents (Complexone);Radiopharmaceutical Chemistry (Chelating Reagents)
Mol File:1611-35-4.mol
XYLENOL ORANGE Structure
XYLENOL ORANGE Chemical Properties
Melting point 72-76 °C(lit.)
Boiling point 895.1±65.0 °C(Predicted)
density 1.564±0.06 g/cm3(Predicted)
storage temp. -20°C
solubility Solubility Soluble in water, ethanol
pka2.6, 6.4, 6.5, 10.5, 12.3(at 25℃)
form powder
color Brown
PH RangeYellow (6.4) to orange-red (10.4)
λmax580nm
Major ApplicationSolar cells, cosmetics, determination of aluminum,nickel,bismuth,thallium,lead,zinc,palladium,mercury,proteins,lipids
EPA Substance Registry SystemGlycine, N,N'-[(1,1-dioxido-3H-2,1-benzoxathiol-3-ylidene)bis[(6-hydroxy-5-methyl-3,1-phenylene)methylene]]bis[N-(carboxymethyl)- (1611-35-4)
Safety Information
Hazard Codes Xn
Risk Statements 22-41-43
Safety Statements 26-39-24/25
WGK Germany 3
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
XYLENOL ORANGE Usage And Synthesis
Chemical PropertiesRed solid
UsesXylenol Orange is used in method for detecting main content of tungsten oxide.
Purification MethodsIt is generally contaminated with starting material (cresol red) and semi-xylenol orange. Purify it by ion-exchange chromatography using DEAE-cellulose, eluting with 0.1M NaCl solution, which will give the sodium salt [3618-43-7].Cresol Red, semi-xylenol orange and iminodiacetic acid bands elute first. This procedure will give the sodium salt of the dye.To obtain the free acid, dissolve the salt in H2O and acidify it with AcOH. Filter it off, wash it with H2O and dry it first in air and then in a vacuum desiccator over P2O5 in the dark [Sato et al. Anal Chim Acta 94 317 1977]. [Beilstein 19 II 111, 19 III/IV 1135, 19/3 V 461.]
XYLENOL ORANGE Preparation Products And Raw materials
N-ETHYLDIETHANOLAMINE 4,4'-METHYLENEBIS(2,6-DIMETHYLPHENOL) Isopropyl Benzenesulfonate 2-((DIMETHYLAMINO)METHYL)-6-METHYLPHENOL O-CRESOLSULFONPHTHALEIN-3',3''-BIS(METHYLAMINOACETIC ACID SODIUM SALT) 2,4,6-Trimethylphenol Phenol Red 1-(3-METHYLPHENYL)ETHANOL 2-[(DIMETHYLAMINO)METHYL]-4,6-DIMETHYLBENZENOL XYLENOL ORANGE N-BENZYLIMINODIACETIC ACID N-Benzyl-N-methylethanolamine 4,4'-DIHYDROXY-3,3'-DIMETHYLDIPHENYLMETHANE Iminodiacetic acid PHENYL-M-TOLYL-METHANOL 4-HYDROXY-3-METHYLBENZYL ALCOHOL N-Methyliminodiacetic acid 3-METHYL-N-METHYLBENZYLAMINE 97

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