ChemicalBook Product Catalog Biochemical Engineering Polypeptide (S)-4-Benzyl-2-oxazolidinone

(S)-4-Benzyl-2-oxazolidinone

(S)-4-Benzyl-2-oxazolidinone Basic information
Product Name:(S)-4-Benzyl-2-oxazolidinone
Synonyms:4-S-BENZYL-OXAZOLIDIN-2-ONE;(S)-4-BENZYL-2-OXAZOLIDINONE;(S)-(-)-4-BENZYL-2-OXAZOLIDONE;(S)-4-Benzyl-2-oxazolodinone, 99% ee:>99%;2-OXAZOLIDINONE, 4-(PHENYLMETHYL)-, (4S)-;(S)-4-Benzyl-2-oxazolidinone, >99% ee;(S)-(+)-4-Benzyloxazolidin-2-one ,99%;(S)-4-Benzyl-2-oxazo
CAS:90719-32-7
MF:C10H11NO2
MW:177.2
EINECS:618-632-6
Product Categories:Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives;Oxazolidinone;Chiral Compounds;chiral;Aromatics Compounds;Asymmetric Synthesis;Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Chiral chemicals;Peptide;Aromatics;Chiral Reagents;Heterocycles;aliskiren;90719-32-7
Mol File:90719-32-7.mol
(S)-4-Benzyl-2-oxazolidinone Structure
(S)-4-Benzyl-2-oxazolidinone Chemical Properties
Melting point 86-88 °C(lit.)
alpha -62 º (C=1, CHCl3)
Boiling point 309.12°C (rough estimate)
density 1.1607 (rough estimate)
refractive index -14.5 ° (C=5, MeOH)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Crystalline Powder
pka12.78±0.40(Predicted)
color White to very slightly yellow
optical activity[α]20/D 63°, c = 1 in chloroform
Water Solubility Insoluble in water.
Sensitive Hygroscopic
BRN 3649667
InChIKeyOJOFMLDBXPDXLQ-VIFPVBQESA-N
CAS DataBase Reference90719-32-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-36-26-37/39
WGK Germany 3
F 3-10
HS Code 29349990
MSDS Information
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(S)-4-Benzyl-2-oxazolidinone English
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(S)-4-Benzyl-2-oxazolidinone Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(S)-(-)-4-Benzyl-2-oxazolidinone is used in chiral auxiliary asymmetric alkylation. It has been used in the synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides. It was used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.
UsesAs an oxazolidinone, (S)-4-Benzyl-2-Oxazolidinone can be used in chiral auxiliary asymetric synthesis.
DefinitionChEBI: (S)-4-BENZYL-2-OXAZOLIDINONE is a member of benzenes.
(S)-4-Benzyl-2-oxazolidinone Preparation Products And Raw materials
Preparation Products4-Benzyl-2-oxo-oxazolidine-3-carbonyl chloride-->(S)-4-Benzyl-3-propionyl-2-oxazolidinone-d3-->(S)-4-benzyl-3-(5,5,5-trifluoropentanoyl)oxazolidin-2-one
Oxazolidinone (N-ACETYL)-(4R)-BENZYL-2-OXAZOLIDINONE Dimethylbenzylcarbinyl acetate N-(DIETHYLPHOSPHONOACETYL) (4S)-BENZYL-2-OXAZOLIDINONE BOC-PHE-N-CARBOXYANHYDRIDE (S)-(-)-4-(4-HYDROXYBENZYL)-2-OXAZOLIDINONE (N-CHLOROACETYL)-(4S)-BENZYL-2-OXAZOLIDINONE (S)-4-BENZYL-2-OXAZOLIDINONE LITHIUM SALT (S)-(-)-[(4-METHOXYPHENYL)METHYL]-2-OXAZOLIDINONE Phenylacetone (S)-(-)-5,5-DIPHENYL-4-BENZYL-2-OXZOLIDINONE (N-CROTONYL)-(4S)-ISOPROPYL-2-OXAZOLIDINONE (S)-(-)-4-Benzyl-5,5-dimethyl-2-oxazolidinone N-(ISOTHIOCYANOACETYL)-(4R)-BENZYL-2-OXAZOLIDINONE (4S)-(+)-4-Benzyl-3-propionyl-2-oxazolidinone Z-L-Phenylalanine N-carboxyanhydride Benzyl DIBENZYLTOLUENE
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