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| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Basic information |
| Product Name: | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER | | Synonyms: | NORBORNADIENE RHODIUM(1) CHLORIDE;NORBORNADIENE RHODIUM(I) CHLORIDE DIMER;RHODIUM(I) CHLORIDE 2,5-NORBORNADIENE COMPLEX DIMER;Chloronorbornadienerhodium(I)dimer,99%;di-ae-chlorobis(norbornadiene) dirhodium(i);bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]di-mu-chlorodirhodium;BICYCLO(2.2.1)HEPTA-2,5-DIENE-RHODIUM(I);Chloro(norbornadiene)rhodium(I), dimer, 99.9% | | CAS: | 12257-42-0 | | MF: | C14H16Cl2Rh28* | | MW: | 460.99 | | EINECS: | 235-510-4 | | Product Categories: | organometallic complexes;Rh;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds | | Mol File: | 12257-42-0.mol | ![(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Structure](CAS/GIF/12257-42-0.gif) |
| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Chemical Properties |
| Melting point | 239-241°C (dec.) | | storage temp. | 2-8°C | | form | Powder | | color | yellow to orange | | Water Solubility | Slightly soluble in acetone, chloroform, methanol and insoluble in water. | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Usage And Synthesis |
| Chemical Properties | mustard yellow crystals | | Uses | Di-μ-chlorobis(norbornadiene)dirhodium(I) is used as catalysts in olefin hydroformylation, olefin hydrogenation and olefin isomerization | | Purification Methods | It recrystallises from hot CHCl3/pet ether as fine crystals soluble in CHCl3 and *C6H6 but is almost insoluble in Et2O or pet ether. [Abel et al. J Chem Soc 3178 1959.] |
| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Preparation Products And Raw materials |
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